US4070530A
Expired / Lapsed
US
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Catalytic amination of polymeric polyols and resulting amino substituted polymers
Assignee: Monsanto Co
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Filing: 1975-10-30
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Granted: 1978-01-24
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Expires: 1995-10-30
Abstract
Abstract Amino substituted polymeric polyols are produced through Group VIII metal catalytic amination of polymers comprising ethylenically unsaturated alcohols and copolymers of said alcohols and vinyl compounds. Polyamines produced by the amination of polyols and/or copolymers thereof having pendant amino and hydroxyl groups or polyamines having said groups fixed to pendant methylene groups are represented by the general formula: <IMAGE> WHERE R is hydrogen or an acyl group; R', R'' are hydrogen or an alkyl group N IS AN INTEGER AND M, P AND W ARE INTEGERS OF 1 OR MORE; AND <IMAGE> +tr <IMAGE> WHERE R and R' are hydrogen or an alkyl group, M IS AN INTEGER N, P, AND I W ARE INTEGERS OF ONE OR MORE.
Inventors
- 👤 Charles F. Hobbs
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 20:05
CPC Classifications
C; C08; C08F; C08F8/00; C08F8/30; C08F8/32; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/3188; Y10T428/31895
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
120 words
A catalytic process for producing polymers having pendant amino and hydroxyl groups comprising the amination of polymers of ethylenically unsaturated alcohols selected from vinyl and allyl alcohols, and copolymers of said alcohols and vinyl compounds selected from the group consisting of vinyl esters of monocarboxylic acids and styrene, said process comprising contacting said polymers of ethylenically unsaturated alcohols or copolymers with at least one of ammonia, mono- and di- aliphatic amines in the presence of a Group VIII metal hydrogenation catalyst, at a temperature of from 125° C to 300° C and a pressure of from about 500 to 2500 psig, said unsaturated alcohol polymers and copolymers having a weight average molecular weight of from about 1700 to about 115,000.
Claim 2
Dependent Claim
120 words
A catalytic process for producing polymers having pendant amino and hydroxyl groups comprising the amination of polymers of ethylenically unsaturated alcohols selected from vinyl and allyl alcohols, and copolymers of said alcohols and vinyl compounds selected from the group consisting of vinyl esters of monocarboxylic acids and styrene, said process comprising contacting said polymers of ethylenically unsaturated alcohols or copolymers with at least one of ammonia, mono- and di- aliphatic amines in the presence of a Group VIII metal hydrogenation catalyst, at a temperature of from 125° C to 300° C and a pressure of from about 500 to 2500 psig, said unsaturated alcohol polymers and copolymers having a weight average molecular weight of from about 1700 to about 115,000.
Claim 3
Dependent Claim
14 words
The process according to claim 1 wherein the Group VIII metal catalyst is nickel.
Claim 4
Dependent Claim
16 words
The process according to claim 1 wherein the polymer of ethylenically unsaturated alcohol is polyvinyl alcohol.
Claim 5
Dependent Claim
18 words
The process according to claim 1 wherein the copolymer is a copolymer of vinyl alcohol and vinyl acetate.
Claim 6
Dependent Claim
17 words
The process according to claim 1 wherein the copolymer is a copolymer of allyl alcohol and styrene.
Claim 7
Dependent Claim
116 words
Amino substituted polymeric polyols of enhanced emulsifying capability having the general formula ##STR7## where R is hydrogen or an acyl group: R' and R" are hydrogen or an alkyl group, n is an integer and m, p and w are integers of 1 or more, produced by the catalytic amination of polymers consisting of polyvinyl alcohol and copolymers of vinyl alcohol and vinyl acetate having a weight average molecular weight of from about 1700 to about 115,000 with at least one of ammonia, mono- and di-aliphatic amines in the presence of a Group VIII metal hydrogenation catalyst at a temperature of from 125° to 300° C and a pressure of from about 500 to 2500 psig.
Claim 8
Dependent Claim
116 words
Amino substituted polymeric polyols of enhanced emulsifying capability having the general formula ##STR7## where R is hydrogen or an acyl group: R' and R" are hydrogen or an alkyl group, n is an integer and m, p and w are integers of 1 or more, produced by the catalytic amination of polymers consisting of polyvinyl alcohol and copolymers of vinyl alcohol and vinyl acetate having a weight average molecular weight of from about 1700 to about 115,000 with at least one of ammonia, mono- and di-aliphatic amines in the presence of a Group VIII metal hydrogenation catalyst at a temperature of from 125° to 300° C and a pressure of from about 500 to 2500 psig.
Claim 9
Dependent Claim
37 words
The amino substituted polymeric polyols according to claim 6 wherein the acyl group has from 1 to about 20 carbon atoms per group and the alkyl group has from 1 to about 20 carbon atoms per group.
Claim 10
Dependent Claim
95 words
Amino substituted polyols having the general formula ##STR8## where R' and R" are hydrogen or an alkyl group and m, n, p and w are integers of 1 or more, produced by the catalytic amination of copolymers of styrene and allyl alcohol having a weight average molecular weight of from about 1700 to about 115,000 with at least one of ammonia, mono- and di- aliphatic amines in the presence of a Group VIII metal hydrogenation catalyst at a temperature of from 125° to 300° C and a pressure of from about 500 to 2500 psig.
Claim 11
Dependent Claim
95 words
Amino substituted polyols having the general formula ##STR8## where R' and R" are hydrogen or an alkyl group and m, n, p and w are integers of 1 or more, produced by the catalytic amination of copolymers of styrene and allyl alcohol having a weight average molecular weight of from about 1700 to about 115,000 with at least one of ammonia, mono- and di- aliphatic amines in the presence of a Group VIII metal hydrogenation catalyst at a temperature of from 125° to 300° C and a pressure of from about 500 to 2500 psig.
Claim 12
Dependent Claim
23 words
The amino substituted polymeric polyols according to claim 8 wherein the alkyl group has from 1 to about 20 carbon atoms per group.
References Cited (Backward Citations)
CA629380A
Cited
US2632757A
Cited
US2628221A
Cited
US2648717A
Cited
GB844448A
Cited
DE1037851B
Cited
US2972606A
Cited
US3117951A
Cited
US3410811A
Cited
FR1575557A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-01-23 | 1981-07-25 | 1982-01-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-01-23 | 1985-07-25 | 1986-01-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-01-23 | 1989-07-25 | 1990-01-24 | $7700.00 | Window Closed / Lapsed |