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US4053382A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid junction of reference electrode

Assignee: Horiba Ltd
•
Filing: 1976-02-06
•
Granted: 1977-10-11
•
Expires: 1996-02-06
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Abstract

Abstract An improved liquid junction for a reference electrode is provided. It is characterized by forming a hydrophilic layer by treatment of only the surface of a liquid junction of a polymer of tetrafluoroethylene.

Inventors

  • 👤 Hiroshi Maruyama
  • 👤 Masashi Watanabe

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 16:21
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/28; G01N27/40; G01N27/401

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 46 words
In a reference electrode comprising an internal electrode, an internal liquid and a liquid junction structure for separating said internal liquid from a liquid sample to be measured, the improvement wherein said junction structure comprises polytetrafluoroethylene having a hydrophillic layer on the liquid junction surfaces thereof.
Claim 2
Dependent Claim 46 words
In a reference electrode comprising an internal electrode, an internal liquid and a liquid junction structure for separating said internal liquid from a liquid sample to be measured, the improvement wherein said junction structure comprises polytetrafluoroethylene having a hydrophillic layer on the liquid junction surfaces thereof.
Claim 3
Dependent Claim 19 words
A reference electrode according to claim 1 wherein the liquid junction is disposed at the base of said electrode.
Claim 4
Dependent Claim 20 words
A reference electrode according to claim 1 wherein the liquid junction is disposed at the side wall of said electrode.
Claim 5
Dependent Claim 20 words
A reference electrode according to claim 1 wherein the hydrophylic layer is formed by the reaction of sodium on polytetrafluoroethylene.
Claim 6
Dependent Claim 18 words
A reference electrode according to claim 4 wherein said reaction is performed in an organic solvent comprising naphthalene.

References Cited (Backward Citations)

CA878722A Cited
US3498899A Cited
US3856649A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-10-10 1981-04-11 1981-10-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-10-10 1985-04-11 1985-10-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-10-10 1989-04-11 1989-10-11 $7700.00 Window Closed / Lapsed

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