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US4046712A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalysts sputtered on substantially nonporous low surface area particulate supports

Assignee: United Kingdom Atomic Energy Authority
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Filing: 1975-06-16
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Granted: 1977-09-06
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Expires: 1995-06-16
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Abstract

Abstract In catalytic gas phase reactions there is used a catalyst comprising a sputtered deposit of catalytic material equivalent to between 0.5 and 5 monatomic layers upon a hard, substantially non-porous substrate. The substrate being hard and non-porous is of low surface area, that is not greater than 20 square meters per gram, and preferably comprises particles having a size in the range 0.1 micron to 0.5 centimeters.

Inventors

  • 👤 James Anthony Cairns
  • 👤 Richard Stuart Nelson
  • 👤 Rhydwyn William Barnfield

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 19:12
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01J; B01J23/00; B01J23/38; B01J23/40; B01J23/42; B01J37/00; B01J37/34; B01J37/341; B01J37/347; F; F01; F01N; F01N2330/00; F01N2330/30; F01N2330/40

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 111 words
A catalyst comprising a hard, substantially non-porous particulate substrate selected from the group consisting of ceramic material and carbon and having a mean particle diameter within the size range 0.1 micron to 0.5 centimeters and a surface area not greater than approximately 20 square meters per gram, and a sputtered deposit of catalytic material comprising one or more of the metals from the group platinum, rhodium, palladium, ruthenium, osmium and iridium upon the substrate, said deposit of said catalytic material having been deposited by bombardment of said catalytic material with energetic ions, the bombardment dislodging atoms of said catalytic material which are then deposited as an atomic dispersion upon the substrate.
Claim 2
Dependent Claim 111 words
A catalyst comprising a hard, substantially non-porous particulate substrate selected from the group consisting of ceramic material and carbon and having a mean particle diameter within the size range 0.1 micron to 0.5 centimeters and a surface area not greater than approximately 20 square meters per gram, and a sputtered deposit of catalytic material comprising one or more of the metals from the group platinum, rhodium, palladium, ruthenium, osmium and iridium upon the substrate, said deposit of said catalytic material having been deposited by bombardment of said catalytic material with energetic ions, the bombardment dislodging atoms of said catalytic material which are then deposited as an atomic dispersion upon the substrate.
Claim 3
Dependent Claim 32 words
A catalyst as claimed in claim 1, wherein the sputtered deposit of catalytic material comprises a quantity of catalytic material equivalent to between 0.5 and 5 monatomic layers upon the substrate surface.
Claim 4
Dependent Claim 25 words
A catalyst as claimed in claim 1, wherein the surface area of the particulate substrate is not greater than approximately 10 square meters per gram.
Claim 5
Dependent Claim 13 words
A catalyst as claimed in claim 1, wherein the ceramic material comprises alumina.

References Cited (Backward Citations)

GB312227A Cited
US2223777A Cited
US2745812A Cited
US3341936A Cited
US3472751A Cited
US3795783A Cited
US3801368A Cited
US3808109A Cited
US3773894A Cited
US3767551A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-09-05 1981-03-07 1981-09-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-09-05 1985-03-07 1985-09-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-09-05 1989-03-07 1989-09-06 $7700.00 Window Closed / Lapsed

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