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US4042536A Expired / Lapsed US ⏱️ 0.0 years remaining

Inorganic-organic plastic

Assignee: Bayer AG
•
Filing: 1974-11-26
•
Granted: 1977-08-16
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Expires: 1994-11-26
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Abstract

Abstract An inorganic-organic plastic having improved strength, elasticity, dimensional stability with increase in temperature and flame resistance and adapted for use in filling cracks and cavities and for making materials useful in the building industry is prepared by (1) premixing (c) an organic compound having at least one reactive hydrogen and at least one ionic group or at least one non-ionic hydrophilic group with (b) an aqueous silicate and then mixing the resulting mixture with (a) an organic polyisocyanate or (2) mixing (a), (b) and (c) simultaneously and reacting the mixture thus obtained to form a colloidal xerosol.

Inventors

  • 👤 Dieter Dieterich
  • 👤 Peter Markusch
  • 👤 Helmut Reiff

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 15:06
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/30; C08G18/38; C08G18/3893; C08G18/3895; C08G18/08; C08G18/0804; C08G18/302; C08K; C08K3/00; C08K3/34; Y; Y10; Y10S; Y10S521/00; Y10S521/906

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 231 words
A process for producing an inorganic-organic plastic with high strength, elasticity, dimensional stability under heat, and flame resistance, which is a composite material of a polymer/polysilicic acid gel, said composite being in the form of a solid/solid xerosol, said process comprising mixing and reacting: A. an organic polyisocyanate, B. a silica composition selected from the group consisting of: i. an aqueous alkali metal silicate containing about 20 - 70% by weight of said alkali metal silicate; ii. an aqueous silica sol having a solids content from 20 to 50%, and iii. mixtures thereof, C. an organic compound which contains i. at least one hydrogen atom capable of reacting with an isocyanate group, and ii. at least one group selected from the group consisting of: a. an ionic group, b. a group capable of forming an ionic group in the presence of an alkali metal silicate, and c. non-ionic hydrophilic groups, said non-ionic hydrophilic group being polyether groups which are built up from ethylene oxide to an extent of at least 10% by weight, with the proviso that if said organic compound contains non-ionic hydrophilic groups, said organic compound contains only one hydrogen atom capable of reacting with an isocyaanate group, said mixing being carried out in such a way that either components (B) and (C) are mixed prior to mixing with (A), or components (A), (B) and (C) are mixed simultaneously.
Claim 2
Dependent Claim 231 words
A process for producing an inorganic-organic plastic with high strength, elasticity, dimensional stability under heat, and flame resistance, which is a composite material of a polymer/polysilicic acid gel, said composite being in the form of a solid/solid xerosol, said process comprising mixing and reacting: A. an organic polyisocyanate, B. a silica composition selected from the group consisting of: i. an aqueous alkali metal silicate containing about 20 - 70% by weight of said alkali metal silicate; ii. an aqueous silica sol having a solids content from 20 to 50%, and iii. mixtures thereof, C. an organic compound which contains i. at least one hydrogen atom capable of reacting with an isocyanate group, and ii. at least one group selected from the group consisting of: a. an ionic group, b. a group capable of forming an ionic group in the presence of an alkali metal silicate, and c. non-ionic hydrophilic groups, said non-ionic hydrophilic group being polyether groups which are built up from ethylene oxide to an extent of at least 10% by weight, with the proviso that if said organic compound contains non-ionic hydrophilic groups, said organic compound contains only one hydrogen atom capable of reacting with an isocyaanate group, said mixing being carried out in such a way that either components (B) and (C) are mixed prior to mixing with (A), or components (A), (B) and (C) are mixed simultaneously.
Claim 3
Dependent Claim 17 words
The process of claim 1, wherein the organic polyisocyanate is the phosgenation product of an aniline-formaldehyde condensation.
Claim 4
Dependent Claim 21 words
The process of claim 1, wherein the proportion by weight of component (A) to component (B) is between 70:30 and 20:80.
Claim 5
Dependent Claim 38 words
The process of claim 1, wherein the quantity of groups (C)(ii)(a) or (b) is 2-200 milliequivalents per 100 grams of components (A), or the non-ionic hydrophilic groups of component (C) comprises 1-50% by weight based on component (A).
Claim 6
Dependent Claim 24 words
The process of claim 1, wherein compounds in addition to isocyanates which effect hardening of the water soluble silicates are included in the mixture.
Claim 7
Dependent Claim 39 words
The process of claim 1 wherein 0-40% by weight of an inert liquid boiling in the range of -25° to +80° C is included in the reaction mixture as a blowing agent and the reaction proceeds with concomitant foaming.
Claim 8
Dependent Claim 19 words
The process of claim 1, wherein 0.001 - 10% by weight of activator is included in the reaction mixture.
Claim 9
Dependent Claim 18 words
The process of claim 1, wherein 0-20% by weight of foam stabilizer is included in the reaction mixture.
Claim 10
Dependent Claim 18 words
The process of claim 1, wherein 0-20% by weight of emulsifying agent is included in the reaction mixture.
Claim 11
Dependent Claim 20 words
The process of claim 1, wherein an inorganic or organic particulate or pulverulent material is included in the reaction mixture.
Claim 12
Dependent Claim 99 words
The process of claim 1, wherein the organic compound (C) is a compound of the formula: X -- R -- Y wherein X = --oh, --sh, --cooh, --nhr 1 r = c 1 -c 20 -alkylene, ##STR7## R 1 = --H, C 1 -C 12 -alkyl, ##STR8## Y = --SO 3 H, --COOH, --SO 3 .sup.( - ), --OSO 3 .sup.( - ), --C00.sup.( - ), NR 3 1 ( + ), --O--(--CH 2 --CH 2 --O)-- n R 1 , or, ##STR9## with at least 10% --O(--CH 2 --CH 2 --O--)-- n R 1 blocks, n = 2-100.
Claim 13
Dependent Claim 15 words
The process of claim 1, wherein said silica compound is an aqueous alkali metal silicate.
Claim 14
Dependent Claim 9 words
The product produced by the process of claim 12.
Claim 15
Dependent Claim 9 words
The product of the process produced by claim 1.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-08-15 1981-02-14 1981-08-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-08-15 1985-02-14 1985-08-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-08-15 1989-02-14 1989-08-16 $7700.00 Window Closed / Lapsed

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