US4038257A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Urethane modified acrylate resin and process for the production thereof
Assignee: Toyobo Co Ltd
•
Filing: 1975-09-19
•
Granted: 1977-07-26
•
Expires: 1995-09-19
Abstract
Abstract A urethane modified acrylate resin and the process for the production of the said urethane modified acrylate resin, wherein the said urethane modified acrylate is expressed by the following general formula (I), ##STR1## (WHEREIN R 1 is a terephthalic oligoester residue, R 2 is an organic diisocyanate residue, R 3 is a polyhydric alcohol residue, R 4 is a hydrogen atom or a methyl group, m is a number not more than 5 and n is an integer from 1 through 4), which is characterized by high elongation, high strength and excellent corrosion resistance and are useful for the production of castings, moldings, adhesives, coatings, primers, varnishes, inks and the like.
Inventors
- 👤 Hajime Suzuki
- 👤 Hideo Miyake
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 16:39
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/675; C08F; C08F120/00; C08F120/02; C08F120/10; C08F120/34; C08F120/36; C08G18/40; C08G18/42; C08G18/4205; C08G18/4208; C08G18/4211; C08G18/671; C08G18/672; C08G18/673
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
62 words
A urethane modified acrylate which is expressed by the following general formula (I), ##STR3## (where R 1 is a terephthalic oligoester residue, R 2 is an organic diisocyanate residue, R 3 is a polyhydric alcohol residue, R 4 is a hydrogen atom or methyl group, m is a number not more than 5 and n is an integer from 1 through 4).
Claim 2
Dependent Claim
62 words
A urethane modified acrylate which is expressed by the following general formula (I), ##STR3## (where R 1 is a terephthalic oligoester residue, R 2 is an organic diisocyanate residue, R 3 is a polyhydric alcohol residue, R 4 is a hydrogen atom or methyl group, m is a number not more than 5 and n is an integer from 1 through 4).
Claim 3
Dependent Claim
44 words
The urethane modified acrylate according to claim (1), wherein the R 1 is the general formula (I) is a residue derived from a terephthalic oligoester having an average molecular weight of from 200 to 2,000 and having an acid value of less than 20.
Claim 4
Dependent Claim
43 words
The urethane modified acrylate according to claim (1), wherein the R 1 in the general formula (I) is a residue derived from a terephthalic bisglycolester having a molecular weight of from 254 to 2,000 and having an acid value of less than 20.
Claim 5
Dependent Claim
62 words
The urethane modified acrylate according to claim (1), wherein the R 1 in the general formula (I) is a residue derived from a terephthalic oligoester having an average molecular weight of from 200 to 2,000 and having an acid value of less than 20 which is obtained by the alcoholysis of a high molecular weight terephthalic saturated polyester with a polyhydric alcohol.
Claim 6
Dependent Claim
20 words
A urethane modified acrylate resin consisting of the urethane modified acrylate according to claim (1) and an unsaturated polymerisable monomer.
Claim 7
Dependent Claim
33 words
The urethane modified acrylate resin according to claim (5), wherein the ratio of the urethane modified acrylate and the unsaturated polymerisable monomer falls in the range of from 95:5 to 5:95 by weight.
Claim 8
Dependent Claim
19 words
The urethane modified acrylate resin according to claim (5), wherein the unsaturated polymerisable monomer is a styrene type monomer.
Claim 9
Dependent Claim
138 words
A process for producing a urethane modified acrylate characterized by preparing a prepolymer containing isocyanate end group, wherein the said prepolymer is obtained by reacting one or more compounds selected from the group consisting of a low molecular weight terephthalic oligoester having an acid value of less than 20 and a mixture of the said terephthalic oligoester and a polyhydric alcohol with an organic diisocyanate, in which reaction the sum of the stoichiometric amounts of the hydroxy group and the carboxyl group in the said compound (s) is less than the stoichiometric amount of the isocyanate group of the said organic diisocyanate, or in the form of a formula (OH + COOH)/NCO < 1, and subsequently reacting the said prepolymer with one or more compounds selected from the group consisting of an acrylate and methacrylate containing hydroxyl group.
Claim 10
Dependent Claim
138 words
A process for producing a urethane modified acrylate characterized by preparing a prepolymer containing isocyanate end group, wherein the said prepolymer is obtained by reacting one or more compounds selected from the group consisting of a low molecular weight terephthalic oligoester having an acid value of less than 20 and a mixture of the said terephthalic oligoester and a polyhydric alcohol with an organic diisocyanate, in which reaction the sum of the stoichiometric amounts of the hydroxy group and the carboxyl group in the said compound (s) is less than the stoichiometric amount of the isocyanate group of the said organic diisocyanate, or in the form of a formula (OH + COOH)/NCO < 1, and subsequently reacting the said prepolymer with one or more compounds selected from the group consisting of an acrylate and methacrylate containing hydroxyl group.
Claim 11
Dependent Claim
49 words
The process according to claim (8), wherein the low molecular weight terephthalic oligoester having an acid value of less than 20 is an oligoester having an average molecular weight of 200 to 2,000 prepared by the alcoholysis of a high molecular weight terephthalic saturated polyester with a polyhydric alcohol.
Claim 12
Dependent Claim
30 words
The process according to claim (8), wherein the said two steps of the reaction are carried out in a medium of an unsaturated polymerisable monomer inactive to the isocyanate group.
Claim 13
Dependent Claim
48 words
The process according to claim (8), wherein the stoichiometric amount of the hydroxy group in the compound selected from the group consisting of an acrylate and methacrylate having hydroxyl group is more than the stoichiometric amount of the isocyanate group in the said prepolymer containing isocyanate end group.
Claim 14
Dependent Claim
21 words
The process according to claim (10), wherein the unsaturated polymerisable monomer inactive to the isocyanate group is a styrene type monomer.
Claim 15
Dependent Claim
116 words
A process for producing a urethane modified acrylate characterized by reacting an organic diisocyanate with a compound selected from the group consisting of an acrylate and methacrylate containing hydroxyl group in which reaction the stoichiometric amount of said hydroxy group of the said compound is less than the stoichiometric amount of the isocyanate group of the said organic diisocyanate, or in the form of a formula OH/NCO < 1, and subsequently reacting the prepolymer obtained by the above reaction with one or more compounds selected from the group consisting of a low molecular weight terephthalic oligoester having an acid value of less than 20 and a mixture of the said terephthalic oligoester and a polyhydric alcohol.
Claim 16
Dependent Claim
116 words
A process for producing a urethane modified acrylate characterized by reacting an organic diisocyanate with a compound selected from the group consisting of an acrylate and methacrylate containing hydroxyl group in which reaction the stoichiometric amount of said hydroxy group of the said compound is less than the stoichiometric amount of the isocyanate group of the said organic diisocyanate, or in the form of a formula OH/NCO < 1, and subsequently reacting the prepolymer obtained by the above reaction with one or more compounds selected from the group consisting of a low molecular weight terephthalic oligoester having an acid value of less than 20 and a mixture of the said terephthalic oligoester and a polyhydric alcohol.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-07-25 | 1981-01-24 | 1981-07-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-07-25 | 1985-01-24 | 1985-07-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-07-25 | 1989-01-24 | 1989-07-26 | $7700.00 | Window Closed / Lapsed |