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US4035540A Expired / Lapsed US ⏱️ 0.0 years remaining

Non-woven fabrics bonded with pH sensitive film-forming silane crosslinked acrylate interpolymers

Assignee: Johnson and Johnson
•
Filing: 1975-12-29
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Granted: 1977-07-12
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Expires: 1995-12-29
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Abstract

Abstract A pH-sensitive polymeric composition is used as a binder for other materials, such as webs of non-woven water-dispersible fibers, to produce products which are completely disposable at selected non-neutral pH's. The polymeric composition, which has film-forming characteristics and water-barrier properties at substantially neutral pH's and yet is solubilizable and thus disposable at substantially non-neutral pH's, comprises a silane crosslinked interpolymer of an alkyl acrylate and a monomer interpolymerizable therewith such as, in the preferred alkaline labile embodiment, acrylic acid. The silane crosslinking monomer is preferably 3-(trimethoxysilyl)-propyl methacrylate or 3-(trimethoxysilyl)-propyl acrylate.

Inventors

  • 👤 Robert J. Gander

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 16:58
CPC Classifications
A; A61; A61F; A61F13/00; A61F13/15; A61F13/53; A61F13/534; B; B32; B32B; B32B5/00; B32B5/22; B32B5/24; B32B5/28; C; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/12; A61F13/539; A61F2013/15008; A61F2013/15048; A61F13/15203; A61F13/15211; A61F2013/15227; A61F2013/530131; A61F2013/53445; A61F2013/5395; A61G; A61G9/00; A61G9/003; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24826; Y10T428/24851; Y10T428/31504; Y10T428/31652; Y10T428/31663; Y10T442/00; Y10T442/60; Y10T442/69

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 255 words
A non-woven fabric dispersible in aqueous media having a pH substantially outside the range of about 4.5 to about 8.5 comprising a web of overlapping, intersecting fibers bonded together with a film-forming polymeric composition having water-barrier properties at neutral pH's in the range of between about 4.5 and about 8.5 and solubilizable at a pH substantially outside said neutral pH range, said composition comprising a silane-crosslinked interpolymer of about 0.5 to 5 parts by weight of a first monomer selected from the group consisting of the alkyl acrylates wherein the alkyl group has from one to eight carbon atoms, and about 1 part by weight of a second monomer selected from the group consisting of acrylic acid, methacrylic acid, fumaric acid, maleic acid, maleic anhydride, itaconic acid, dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, diethylaminoethyl acrylate, diethylaminoethyl methacrylate, tert.-butylaminoethyl acrylate and tert.-butylaminoethyl methacrylate, and about 0.9 to 1.5% by weight, based on the combined weight of said first and second monomers, of a crosslinking monomer selected from the group consisting of the silane monomers having the structural formula: ##STR2## wherein: R is selected from the group consisting of CH 3 --, CH 3 CH 2 --, CH 3 O-- and CH 3 CH 2 O--; R 1 and R 2 are each selected from the group consisting of CH 3 -- and CH 3 CH 2 --; R 3 is selected from the group consisting of H--, CH 3 -- and CH 3 CH 2 --; and n is 0 or a positive integer not greater than 8.
Claim 2
Dependent Claim 255 words
A non-woven fabric dispersible in aqueous media having a pH substantially outside the range of about 4.5 to about 8.5 comprising a web of overlapping, intersecting fibers bonded together with a film-forming polymeric composition having water-barrier properties at neutral pH's in the range of between about 4.5 and about 8.5 and solubilizable at a pH substantially outside said neutral pH range, said composition comprising a silane-crosslinked interpolymer of about 0.5 to 5 parts by weight of a first monomer selected from the group consisting of the alkyl acrylates wherein the alkyl group has from one to eight carbon atoms, and about 1 part by weight of a second monomer selected from the group consisting of acrylic acid, methacrylic acid, fumaric acid, maleic acid, maleic anhydride, itaconic acid, dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, diethylaminoethyl acrylate, diethylaminoethyl methacrylate, tert.-butylaminoethyl acrylate and tert.-butylaminoethyl methacrylate, and about 0.9 to 1.5% by weight, based on the combined weight of said first and second monomers, of a crosslinking monomer selected from the group consisting of the silane monomers having the structural formula: ##STR2## wherein: R is selected from the group consisting of CH 3 --, CH 3 CH 2 --, CH 3 O-- and CH 3 CH 2 O--; R 1 and R 2 are each selected from the group consisting of CH 3 -- and CH 3 CH 2 --; R 3 is selected from the group consisting of H--, CH 3 -- and CH 3 CH 2 --; and n is 0 or a positive integer not greater than 8.
Claim 3
Dependent Claim 29 words
The non-woven fabric of claim 1 wherein said first monomer is ethyl acrylate and said silane monomer is selected from the group consisting of 3-(trimethoxysilyl)-propyl methacrylate and 3-(trimethoxysilyl)-propyl acrylate.
Claim 4
Dependent Claim 30 words
The non-woven fabric of claim 2 wherein said second monomer is selected from the group consisting of acrylic acid, methacrylic acid, fumaric acid, maleic acid, maleic anhydride and itaconic acid.
Claim 5
Dependent Claim 30 words
The non-woven fabric of claim 2 wherein said second monomer is selected from the group consisting of dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, diethylaminoethyl acrylate, diethylaminoethyl methacrylate, tert.-butylaminoethyl acrylate and tert.-butylaminoethyl methacrylate.
Claim 6
Dependent Claim 13 words
The non-woven fabric of claim 3 wherein said second monomer is acrylic acid.
Claim 7
Dependent Claim 13 words
The non-woven fabric of claim 4 wherein said second monomer is dimethylaminoethyl methacrylate.
Claim 8
Dependent Claim 18 words
The non-woven fabric of claim 1 wherein said composition is distributed in said web in a predetermined pattern.

References Cited (Backward Citations)

GB1127625A Cited
US3716399A Cited
US3480016A Cited
US3617362A Cited
US3706697A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-07-11 1981-01-10 1981-07-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-07-11 1985-01-10 1985-07-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-07-11 1989-01-10 1989-07-12 $7700.00 Window Closed / Lapsed

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