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US4022955A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermosetting coating composition comprising a hydroxy acrylate ester copolymer and N-acylpolylactam or N-acylpolyimide

Assignee: Resonac Corp
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Filing: 1975-07-01
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Granted: 1977-05-10
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Expires: 1995-07-01
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Abstract

Abstract When an N-acylpolylactam or N-acylpolyimide compound is incorporated into an acrylic copolymer containing as a functional group a hydroxyl group, a thermosetting resinous composition suitable for the production of a paint, especially a powder paint, is obtained. A powder paint prepared from this resinous composition does not cause blocking below 50° C. and therefore, it has a very good storage stability. The powder paint has a free flowability at room temperature and exhibits good melt flow characteristics when heated above 130° C. for baking. Coating films prepared from this coating composition are excellent in the mechanical resistance, adhesion to the substrate, weather resistance, corrosion resistance and solvent resistance. When said acrylic copolymer further contains as a functional group a carboxyl or glycidyl group, the resulting resinous composition has further improved properties useful for a paint.

Inventors

  • 👤 Hiroshi Nishizawa
  • 👤 Minoru Fuzishima

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 19:26
CPC Classifications
C; C09; C09D; C09D157/00; C09D157/04; C08; C08K; C08K5/00; C08K5/16; C08K5/34

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 251 words
A thermosetting coating composition comprising (A) 100 parts by weight of a copolymer obtained by copolymerizing (a) 5 to 40% by weight of at least one unsaturated compound containing a hydroxyl group selected from the group consisting of hydroxyalkyl acrylates, hydroxyalkyl methacrylates and acrylic and methacrylic esters of glycols, glycerine, trimethylol propane and pentaerythritol and (b) 60 and 95% by weight of an unsaturated compound copolymerizable with said compound (a) and being at least one member selected from the group consisting of styrene type monomers, alkyl acrylates, alkyl methacrylates, vinyl acetate, acrylonitrile and acrylamide, said copolymer (A) having a number average molecular weight of 2,000 to 150,000 and (B) 5 to 40 parts by weight of at least one member selected from the group consisting of an N-acylpolylactam compound represented by the general formula ##STR11## wherein R is an alkylene group having 2 to 12 carbon atoms, which may include 1 to 2 nitrogen or oxygen atoms, or may contain locally an unsaturated linkage, a di- to tetra-valent benzene nucleus, which may have a substituent on the benzene nucleus, or a di- to trivalent heterocyclic residue having 3 to 15 carbon atoms; R' stands for an alkylene group having 1 to 11 carbon atoms; and n is an integer of 2 to 4, an N-acylopolyimide compound represented by the general formula ##STR12## wherein R and n are as defined above and R" stands for an alkylene group having 1 to 11 carbon atoms or a divalent benzene nucleus, and mixtures thereof.
Claim 2
Dependent Claim 251 words
A thermosetting coating composition comprising (A) 100 parts by weight of a copolymer obtained by copolymerizing (a) 5 to 40% by weight of at least one unsaturated compound containing a hydroxyl group selected from the group consisting of hydroxyalkyl acrylates, hydroxyalkyl methacrylates and acrylic and methacrylic esters of glycols, glycerine, trimethylol propane and pentaerythritol and (b) 60 and 95% by weight of an unsaturated compound copolymerizable with said compound (a) and being at least one member selected from the group consisting of styrene type monomers, alkyl acrylates, alkyl methacrylates, vinyl acetate, acrylonitrile and acrylamide, said copolymer (A) having a number average molecular weight of 2,000 to 150,000 and (B) 5 to 40 parts by weight of at least one member selected from the group consisting of an N-acylpolylactam compound represented by the general formula ##STR11## wherein R is an alkylene group having 2 to 12 carbon atoms, which may include 1 to 2 nitrogen or oxygen atoms, or may contain locally an unsaturated linkage, a di- to tetra-valent benzene nucleus, which may have a substituent on the benzene nucleus, or a di- to trivalent heterocyclic residue having 3 to 15 carbon atoms; R' stands for an alkylene group having 1 to 11 carbon atoms; and n is an integer of 2 to 4, an N-acylopolyimide compound represented by the general formula ##STR12## wherein R and n are as defined above and R" stands for an alkylene group having 1 to 11 carbon atoms or a divalent benzene nucleus, and mixtures thereof.
Claim 3
Dependent Claim 33 words
A thermosetting coating composition as set forth in claim 1 wherein the copolymer (A) has a softening point of 40° to 120° C. and a number average molecular weight of 2,000 to 30,000.
Claim 4
Dependent Claim 52 words
A thermosetting coating composition as set forth in claim 1 wherein the compound (a) is at least one member selected from the group consisting of 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate, ethylene glycol monoacrylate, ethylene glycol monomethacrylate, propylene glycol monoacrylate, propylene glycol monomethacrylate, butylene glycol monoacrylate and butylene glycol monomethacrylate.
Claim 5
Dependent Claim 48 words
A thermosetting coating composition as set forth in claim 1 wherein the compound (b) is at least one member selected from the group consisting of styrene, vinyl toluene, α-methylstyrene, methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, vinyl acetate, acrylonitrile and acrylamide.
Claim 6
Dependent Claim 39 words
A thermosetting coating composition as set forth in claim 1 wherein the compound (B) is at least one member selected from the group consisting of terephthaloyl-bis-(N-pyrrolidone), adipoyl-bis-(N-pyrrolidone), terephthaloyl-bis-(N-caprolactam), isophthaloyl-bis-N-caprolactam, sebacoyl-bis-(N-caprolactam), adipoyl-bis-(N-caprolactam), isophthaloyl-bis-(N-succinimide), sebacoyl-bis-(N-phthalimide), fumaloyl-bis-(N-caprolactam), fumaloyl-bis-(N-succinimide), diglycoyl-bis-(N-caprolactam), diglycoyl-bis-(N-succinimide), trimelloyl-tris-(N-caprolactam), ##STR13##

References Cited (Backward Citations)

US2993021A Cited
US3813367A Cited
US3597401A Cited
US3660327A Cited
US3803101A Cited
US3733302A Cited
US3759876A Cited
US3726945A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-05-09 1980-11-08 1981-05-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-05-09 1984-11-08 1985-05-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-05-09 1988-11-08 1989-05-10 $7700.00 Window Closed / Lapsed

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