Abstract A layer composition, which may be used for making shoes, upholstery or the like, comprising a carrier layer and a cover layer adhering thereto. The cover layer essentially consists of a synthetic resin material which bubbles are imbedded. The shells of the bubbles consists of a thermoplastic synthetic resin material other than the material of the cover layer. Preferably the shell of the bubbles consists of an elastic copolymer of polyvinylidene chloride and/or of a copolymer of polyvinyl chloride. The bubbles are bonded to the material of the cover layer and have hollow cores containing a gas, preferably air. The volume of the hollow cores amounts to at least 25%, preferably 50 to 85%, of the total volume of the cover layer.
A composite leather multilayer structure for shoe material and the lime comprising a natural leather carrier layer and a cover layer bonded to said leather carrier layer and consisting of a polyurethane synthetic-resin matrix having bubbles of diameters of substantially 0.009 to 0.6 mm distributed therein, said bubbles each being elastically deformable and having a shell of polyvinylidene chloride copolymer synthetic-resin thermoplastic material and enclosing a gas-filled space, said gas-filled spaces constituting 50 to 85% of the total volume of said cover layer, said cover layer having a surface remote from said carrier layer forming a leather-like pattern.
Claim 2
Dependent Claim
98 words
A composite leather multilayer structure for shoe material and the lime comprising a natural leather carrier layer and a cover layer bonded to said leather carrier layer and consisting of a polyurethane synthetic-resin matrix having bubbles of diameters of substantially 0.009 to 0.6 mm distributed therein, said bubbles each being elastically deformable and having a shell of polyvinylidene chloride copolymer synthetic-resin thermoplastic material and enclosing a gas-filled space, said gas-filled spaces constituting 50 to 85% of the total volume of said cover layer, said cover layer having a surface remote from said carrier layer forming a leather-like pattern.
Claim 3
Dependent Claim
19 words
The multilayer structure defined in claim 1 wherein said diameters are in the range of 0.01 to 0.06 mm.
Claim 4
Dependent Claim
17 words
The multilayer structure defined in claim 1 wherein said bubbles are only loosely bonded to said matrix.
Claim 5
Dependent Claim
31 words
The multilayer structure defined in claim 3, further comprising a layer of an antibonding agent along the outer surfaces of said bubbles for resisting bonding between said shells and said matrix.
Claim 6
Dependent Claim
25 words
The multilayer structure defined in claim 4 wherein said antibonding agent is selected from the group which consists of polysiloxanes, fatty acids and fatty alcohols.
Claim 7
Dependent Claim
30 words
The multilayer structure defined in claim 1 wherein the proportion of said spaces in a surface region of said cover layer is greater than that in a central region thereof.
Claim 8
Dependent Claim
16 words
The multilayer structure defined in claim 1 wherein said surface is formed with a finishing layer.