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US4016040A Expired / Lapsed US ⏱️ 0.0 years remaining

Preparation of enzyme-containing beads

Assignee: Colgate Palmolive Co
•
Filing: 1974-11-01
•
Granted: 1977-04-05
•
Expires: 1994-11-01
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Abstract

Abstract Granular free-flowing non-dusting, spherical enzyme-containing beads for use in detergents are prepared by spraying droplets of a blend consisting essentially of a molten nonionic detergent and an enzyme concentrate from a spray nozzle into cool air in a cooling tower to solidify the droplets and form tiny spherical beads.

Inventors

  • 👤 Maung Hla Win
  • 👤 Walter Anthony DiSalvo
  • 👤 Edward Joseph Kenney

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 16:18
CPC Classifications
C; C11; C11D; C11D11/00; C11D11/02; C11D3/00; C11D3/16; C11D3/38; C11D3/386; C11D3/38672

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 157 words
A process for manufacturing free-flowing substantially dust-free, substantially spherical, enzyme-containing beads consisting essentially of a water dispersible solid, fusible, substantially anhydrous, nonionic detergent binder having a melting point up to about 60° C., having dispersed therein an enzyme concentrate consisting essentially of proteolytic enzyme, said binder having a hydrophilic polyethylene oxide chain of 6 to 84 ethylene oxide units, the concentration of the proteolytic enzyme in said beads being sufficient so that the beads contain about 0.1 to 5 Anson units per gram, with substantially all of said beads passing through a 10 mesh U.S. Standard Sieve Series screen and at most about 11.2% of said beads passing through a 100 mesh U.S. Standard Sieve Series screen, which comprises blending a powdered concentrate of said enzyme with said binder in molten form and spraying droplets of said blend through a spray nozzle into cool air in a cooling tower to solidify said droplets and form said beads.
Claim 2
Dependent Claim 157 words
A process for manufacturing free-flowing substantially dust-free, substantially spherical, enzyme-containing beads consisting essentially of a water dispersible solid, fusible, substantially anhydrous, nonionic detergent binder having a melting point up to about 60° C., having dispersed therein an enzyme concentrate consisting essentially of proteolytic enzyme, said binder having a hydrophilic polyethylene oxide chain of 6 to 84 ethylene oxide units, the concentration of the proteolytic enzyme in said beads being sufficient so that the beads contain about 0.1 to 5 Anson units per gram, with substantially all of said beads passing through a 10 mesh U.S. Standard Sieve Series screen and at most about 11.2% of said beads passing through a 100 mesh U.S. Standard Sieve Series screen, which comprises blending a powdered concentrate of said enzyme with said binder in molten form and spraying droplets of said blend through a spray nozzle into cool air in a cooling tower to solidify said droplets and form said beads.
Claim 3
Dependent Claim 32 words
A process according to claim 1 wherein the binder has a melting point in the range of 45° to 60° C. and said blend is sprayed at a temperature below 65° C.
Claim 4
Dependent Claim 60 words
A process according to claim 2 wherein the blend of powdered enzyme concentrate and binder includes about 5 to 50% of enzyme concentrate and 95 to 50% of nonionic detergent and is sprayed at a temperature about 5° C. above the melting point of the binder into cooling air which is at a temperature of about 13° to 24° C.

References Cited (Backward Citations)

US3207666A Cited
US3519570A Cited
US3573170A Cited
US3853780A Cited
US3858854A Cited
US3801463A Cited
US3775331A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-04-04 1980-10-04 1981-04-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-04-04 1984-10-04 1985-04-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-04-04 1988-10-04 1989-04-05 $7700.00 Window Closed / Lapsed

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