US4003707A
Expired / Lapsed
US
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Method and arrangement for measuring the concentration of gases
Assignee: Max-Planck-Gesellschaft zur Förderung der Wissenschaften eV
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Filing: 1976-02-26
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Granted: 1977-01-18
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Expires: 1996-02-26
Abstract
Abstract A method and an arrangement for measuring the concentration of gases in a mple includes the generation of a monochromatic light beam having predetermined color characteristic. An indicator generates light signals indicative of the concentration of the gases in a sample to be measured and includes a light-transmissive surface positioned to be impinged by the monochromatic light beam, a diffusion membrane adapted to be placed in the proximity of a sample and being permeable to a selected gas component thereof, and an indicating substance positioned to be impinged by the monochromatic light beam penetrating the light-transmissive surface and by the gas component penetrating the diffusion membrane. The indicating substance reacts when illuminated by the incident monochromatic light by emitting a resultant light beam having an emitted component which has a color characteristic different from the predetermined color characteristic of the monochromatic light beam. The resultant light beam is conducted away from the indicating substance through the light-transmissive surface. Finally, the emitted component is discriminated from the resultant light beam so that the change in the color characteristic of the indicating substance can be measured and correlated with the concentration of gases in the sample.
Inventors
- 👤 Dietrich W. Lubbers
- 👤 Norbert Opitz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 02:59
CPC Classifications
G; G01; G01N; G01N21/00; G01N21/62; G01N21/63; G01N21/64; G01N21/6428; G01N21/643; G01N2021/6434; Y; Y10; Y10T; Y10T436/00; Y10T436/20; Y10T436/204998; Y10T436/25; Y10T436/25375; Y10T436/255
Claims Analysis
Total Claims: 29
Claim 1
Independent Claim
187 words
A method of measuring the concentration of gases in a sample comprising the steps of generating a monochromatic light beam having a predetermined color characteristic; generating light signals indicative of the concentration of gases in a sample to be measured by positioning an indicator having a light-transmissive surface positioned to be impinged by said monochromatic light beam, a diffusion membrane adapted to be placed in the proximity of a sample and being selectively permeable to a gas component thereof, and an indicating substance positioned to be impinged by the monochromatic light beam penetrating said light-transmissive surface and by said gas component penetrating said diffusion membrane, said indicating substance reacting when illuminated by said incident monochromatic light beam by emitting a resultant light beam having an emitted component which has a color characteristic different from said predetermined color characteristic; conducting said resultant light beam away from said indicating substance through said light-transmissive surface; and discriminating said emitted component from said resultant light beam so that the change in the color characteristic of said indicating substance can be measured and correlated with the concentration of gases in the sample.
Claim 2
Independent Claim
187 words
A method of measuring the concentration of gases in a sample comprising the steps of generating a monochromatic light beam having a predetermined color characteristic; generating light signals indicative of the concentration of gases in a sample to be measured by positioning an indicator having a light-transmissive surface positioned to be impinged by said monochromatic light beam, a diffusion membrane adapted to be placed in the proximity of a sample and being selectively permeable to a gas component thereof, and an indicating substance positioned to be impinged by the monochromatic light beam penetrating said light-transmissive surface and by said gas component penetrating said diffusion membrane, said indicating substance reacting when illuminated by said incident monochromatic light beam by emitting a resultant light beam having an emitted component which has a color characteristic different from said predetermined color characteristic; conducting said resultant light beam away from said indicating substance through said light-transmissive surface; and discriminating said emitted component from said resultant light beam so that the change in the color characteristic of said indicating substance can be measured and correlated with the concentration of gases in the sample.
Claim 3
Dependent Claim
191 words
In an arrangement for measuring the concentration of gases in a sample, a combination comprising means for generating a monochromatic light beam having a predetermined color characteristic; indicating means for generating light signals indicative of the concentration of gases in a sample to be measured, including a light-transmissive surface positioned to be impinged by said monochromatic light beam, a diffusion membrane adapted to be placed in proximity of a sample and being permeable to a selected gas component thereof, and an indicating substance positioned to be impinged by said monochromatic light beam penetrating said light-transmissive surface and by said gas component penetrating said diffusion membrane, said indicating substance reacting when illuminated by said incident monocrhromatic light beam by emitting a resultant light beam having an emitted component which has a color characteristic different from said predetermined color characteristic; means for conducting said resultant light beam away from said indicating substance through said light-transmissive surface; and means for discriminating said emitted component from said resultant light beam so that the change in the color characteristic of said indicating substance can be measured and correlated with the concentration of gases in the sample.
Claim 4
Dependent Claim
191 words
In an arrangement for measuring the concentration of gases in a sample, a combination comprising means for generating a monochromatic light beam having a predetermined color characteristic; indicating means for generating light signals indicative of the concentration of gases in a sample to be measured, including a light-transmissive surface positioned to be impinged by said monochromatic light beam, a diffusion membrane adapted to be placed in proximity of a sample and being permeable to a selected gas component thereof, and an indicating substance positioned to be impinged by said monochromatic light beam penetrating said light-transmissive surface and by said gas component penetrating said diffusion membrane, said indicating substance reacting when illuminated by said incident monocrhromatic light beam by emitting a resultant light beam having an emitted component which has a color characteristic different from said predetermined color characteristic; means for conducting said resultant light beam away from said indicating substance through said light-transmissive surface; and means for discriminating said emitted component from said resultant light beam so that the change in the color characteristic of said indicating substance can be measured and correlated with the concentration of gases in the sample.
Claim 5
Dependent Claim
16 words
The arrangement of claim 2, wherein said indicating substance is sealingly embedded thoughout said diffusion membrane.
Claim 6
Dependent Claim
16 words
The arrangement of claim 2; and further comprising means for controlling the temperature of a sample.
Claim 7
Dependent Claim
11 words
The arrangement of claim 2, wherein the indicating substance is β-methyl-umbelliferon.
Claim 8
Dependent Claim
12 words
The arrangement of claim 2, wherein the indicating substance is Pyrene-butyric acid.
Claim 9
Dependent Claim
17 words
The arrangement of claim 2; and further comprising additional indicating substances intermixed with said first-mentioned indicating substance.
Claim 10
Dependent Claim
15 words
The arrangement of claim 2; and further comprising a reflecting wall located behind said membrane.
Claim 11
Dependent Claim
15 words
The arrangement of claim 2; and further comprising an absorption wall located behind said membrane.
Claim 12
Dependent Claim
22 words
The arrangement of claim 2, wherein sid discriminating means comprises filtering means for permitting substantially only said emitted light to pass through.
Claim 13
Dependent Claim
25 words
The arrangement of claim 2, wherein said indicating means is comprised of a plurality of particles, each comprising said indicating substance and said diffusion membrane.
Claim 14
Dependent Claim
39 words
The arrangement of claim 2; and further comprising additional indicating means adjacent said first-mentioned indicating means, said additional indicating means having a diffusion membrane selectively permeable to another gas component and an indicating substance which reacts with the latter.
Claim 15
Dependent Claim
34 words
The arrangement of claim 12, wherein the diffusion membrane of said first-mentioned indicating means is substantially permeable to oxygen; and wherein the diffusion membrane of said additional indicating means is substantially permeable to carbon-dioxide.
Claim 16
Dependent Claim
48 words
The arrangement of claim 2; wherein said means for generating said monochromatic light beam includes a light-conductive cable for directing said monochromatic light beam towards said indicating means; and wherein said conducting means comprises another light-conductive cable for directing said resultant light beam away from said indicating means.
Claim 17
Dependent Claim
40 words
The arrangement of claim 14; and further comprising additional indicating means located adjacent said first-mentioned indicating means; and wherein said monochromatic light beam comprises two monochromatic components, each being directed by said one light-conductive cable towards said respective indicating means.
Claim 18
Dependent Claim
37 words
The arrangement of claim 15, and wherein both said indicating means respectively emit emitted light components, each being conducted by said other light-conductive cable towards said discrimination means so that each emitted light component is individually measured.
Claim 19
Dependent Claim
32 words
The arrangement of claim 2; and further comprising a portable housing containing said means for generating a monochromatic light beam and said discrimination means for transporting the measuring arrangement to a sample.
Claim 20
Dependent Claim
15 words
The arrangement of claim 17, wherein said indicating means is interchangeably mounted in said housing.
Claim 21
Dependent Claim
15 words
The arrangement of claim 17; and further comprising additional measuring electrodes mounted in said housing.
Claim 22
Dependent Claim
35 words
The arrangement of claim 2, wherein said light-transmissive surface is planar and constitutes an upper layer, and wherein said indicating substance is generally located in a plane intermediate said upper layer and said diffusion membrane.
Claim 23
Dependent Claim
24 words
The arrangement of claim 20, wherein said indicating substance is arranged in a dichroic layer having one side which absorbs said monochromatic light beam.
Claim 24
Dependent Claim
19 words
The arrangement of claim 20, wheren said membrane has a reflective layer on its side facing said indicating substance.
Claim 25
Dependent Claim
19 words
The arrangement of claim 20, wherein said membrane has an absorbing layer on its side facing said indicating substance.
Claim 26
Dependent Claim
36 words
The arrangement of claim 2, wherein said means for generating a monochromatic light beam includes means for modifying the latter into a plurality of separate monochromatic components, each monochromatic component being directed towards said indicating substance.
Claim 27
Dependent Claim
25 words
The arrangement of claim 24, wherein said modifying means comprises a plurality of monochromatic filters, each positioned to be impinged by said monochromatic light beam.
Claim 28
Dependent Claim
25 words
The arrangement of claim 24, wherein said conducting means comprises a plurality of light-reflective elements, each positioned to be impinged by said emitted light component.
Claim 29
Dependent Claim
16 words
The arrangement of claim 26, wherein said discriminating means processes each of said emitted light components.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-01-18 | 1980-07-19 | 1981-01-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-01-18 | 1984-07-19 | 1985-01-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-01-18 | 1988-07-19 | 1989-01-18 | $7700.00 | Window Closed / Lapsed |