Abstract A porous conducting particle, hydrophobic bonded, substrate supported electrode is prewetted with the electrolyte. A D.C. voltage is applied to the electrode to assist in the prewetting with the electrolyte. A soluble catalyst-containing material is then introduced into the electrode structure and the catalyst deposited within the electrode. By appropriate selection of the porous conducting particles and the catalyst-applying techniques, precise control of the location of the catalyst can be obtained. If graphite materials are used as the conducting particles, a catalyst-containing salt is allowed to dissolve in the electrolyte in the prewetted electrode, and the catalyst-containing material is reduced to the metal. If the reduction is done by reaction with a reducing gas such as hydrogen, the catalyst will be deposited only in those regions of the electrode at which there is an electrolyte-reactant gas interface which is in electrical-conducting relationship with the substrate. Alternatively, extremely precise amounts of catalyst can be deposited within the electrode structure by use of a solution of a compound of the catalyst whose wettability with the hydrophobic material varies as the solution evaporates. By this technique almost 100% of the catalyst can be deposited within the electrode structure on the hydrophilic region, with virtually no losses in the hydrophobic material.
A process for introducing a soluble, catalyst containing material into a conducting particle, hydrophobic-bonded electrochemical cell electrode which comprises: a. dissolving said soluble catalyst-containing material in a liquid solution of dissimilar liquids which liquid solution is: i. capable of wetting the hydrophobic bonding material of the electrode at a first composition range of said liquids, ii. incapable of wetting the hydrophobic bonding material at a second composition range of said liquids, and iii. capable of changing from said first composition range to said second composition range on evaporation of said solution; b. contacting said electrode structure with said soluble catalyst-containing material dissolved in the liquid solution in said first composition range, whereby said solution enters the hydrophobic and hydrophilic regions of said electrode structure, and c. evaporating said solution to change its composition from said first composition range to said second composition range whereby said solution withdraws from the hydrophobic bonding material of said electrode structure.
Claim 2
Dependent Claim
156 words
A process for introducing a soluble, catalyst containing material into a conducting particle, hydrophobic-bonded electrochemical cell electrode which comprises: a. dissolving said soluble catalyst-containing material in a liquid solution of dissimilar liquids which liquid solution is: i. capable of wetting the hydrophobic bonding material of the electrode at a first composition range of said liquids, ii. incapable of wetting the hydrophobic bonding material at a second composition range of said liquids, and iii. capable of changing from said first composition range to said second composition range on evaporation of said solution; b. contacting said electrode structure with said soluble catalyst-containing material dissolved in the liquid solution in said first composition range, whereby said solution enters the hydrophobic and hydrophilic regions of said electrode structure, and c. evaporating said solution to change its composition from said first composition range to said second composition range whereby said solution withdraws from the hydrophobic bonding material of said electrode structure.
Claim 3
Dependent Claim
19 words
The process of claim 1 further comprising the step of depositing insoluble catalyst from solution onto the conducting particles.
Claim 4
Dependent Claim
25 words
The process of claim 2 wherein said soluble catalyst containing material is chloroplatinic acid and insoluble platinum catalyst is deposited by reduction with hot hydrogen.
Claim 5
Dependent Claim
35 words
The process of claim 1 wherein said dissimilar liquids are water and an alcohol, said hydrophobic bonding material is PTFE and said porous conducting particles are selected from the group consisting of carbon and graphite.