Battery separators made from polymeric fibers

Claim 1

In a process for producing a melt-blown non-woven mat battery separator wherein a fiber-forming thermoplastic polymer resin is extruded in molten form from orifices of a heated nozzle into a stream of hot inert gas which attenuates said molten resin into fibers that form a fiber stream, and said fibers are collected on a receiver in the path of said fiber stream to form the non-woven mat, the improvement of: a. producing said mat at high resin flow rates, which comprises extruding from said nozzle orifices, at a resin flow rate of at least about 0.1 grams per minute per orifice, a fiber-forming thermoplastic polymer resin degraded to have both an intrinsic viscosity of from about 0.6 to less than 1.4 and an apparent viscosity in said nozzle orifices of from about 50 to about 300 poise; b. collecting said fibers on said receiver in a basis weight of 100 - 400 grams/in. 2 ; c. compacting said fibers to a mat thickness of 10 to 50 mils and a porosity (percent void fraction) greater than 40 percent at a temperature about 5° to 20°F. above the softening point of said thermoplastic and 5° to 35°F below the melting point of said thermoplastics utilizing fixed spacers or shims at i. a pressure of about 1-10 psi, and ii. a time interval of from 0.01 to 30 seconds wherein said spacers or shims prevent large pressures from being applied directly to the mat surfaces, and d. producing a battery separator having an electrical resistance less than 0.040 ohms/in 2 .