US3968093A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for producing partially hydrolyzed polyacrylamide in the presence of alkali metal hydroxide and boric acid
Assignee: Mitsubishi Chemical Corp
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Filing: 1974-05-13
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Granted: 1976-07-06
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Expires: 1994-05-13
Abstract
Abstract A process for producing a partially hydrolyzed polyacrylamide which has a high molecular weight and high water solubility and can be suitably used as a flocculant for water treatment and a size for paper manufacture comprising polymerizing an aqueous solution of an acrylamide monomer in the presence of an alkali metal hydroxide such as sodium hydroxide and boric acid, whereby a partial hydrolysis of the polymer formed is also conducted substantially simultaneously with the polymerization. In an additional embodiment, a maturing of the polyacrylamide produced can be conducted by continuing to heat the polymer solution to increase the hydrolysis percentage.
Inventors
- 👤 Masao Hasegawa
- 👤 Akihisa Furuno
- 👤 Haruhiko Ishikawa
- 👤 Yasuo Ogawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 11:55
CPC Classifications
C; C08; C08F; C08F120/00; C08F120/02; C08F120/52; C08F120/54; C08F120/56
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
50 words
A process for producing partially hydrolyzed polyacrylamide, which comprises polymerizing acrylamide monomer in an aqueous solution in the presence of alkali metal hydroxide and boric acid, whereby the polymer formed is also hydrolyzed simultaneously with said polymerizing and the resulting polymer is of high molecular weight and high water solubility.
Claim 2
Dependent Claim
50 words
A process for producing partially hydrolyzed polyacrylamide, which comprises polymerizing acrylamide monomer in an aqueous solution in the presence of alkali metal hydroxide and boric acid, whereby the polymer formed is also hydrolyzed simultaneously with said polymerizing and the resulting polymer is of high molecular weight and high water solubility.
Claim 3
Dependent Claim
25 words
The process as claimed in claim 1, wherein the concentration of said acrylamide monomer in said aqueous solution is higher than about 18% by weight.
Claim 4
Dependent Claim
26 words
The process as claimed in claim 1, wherein the molar ratio of said alkali metal hydroxide to boric acid is from about 0.8 to about 1.3.
Claim 5
Dependent Claim
24 words
The process as claimed in claim 1, wherein said partially hydrolyzed polyacrylamide is produced as a gel-like polymer having a high tackiness or viscoelasticity.
Claim 6
Dependent Claim
19 words
The process as claimed in claim 4, including further heating said gel-like polymer to increase the hydrolysis percentage thereof.
Claim 7
Dependent Claim
25 words
The process as claimed in claim 5, wherein the further heating of the gel-like polymer is at temperatures of from about 75°C to about 100°C.
Claim 8
Dependent Claim
25 words
The process as claimed in claim 5, wherein the further heating of the gel-like polymer is at temperatures of from about 80° to about 100°C.
Claim 9
Dependent Claim
20 words
The process as claimed in claim 5, wherein said further heating is for a period of 4 to 20 hours.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-07-06 | 1980-01-05 | 1980-07-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-07-06 | 1984-01-05 | 1984-07-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-07-06 | 1988-01-05 | 1988-07-06 | $7700.00 | Window Closed / Lapsed |