US3966847A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Contact lens from hydrophilic gel polymers of polyvinylpyrrolidone and hydroxyalkyl methacrylate
Assignee: Individual
•
Filing: 1974-01-04
•
Granted: 1976-06-29
•
Expires: 1994-01-04
Abstract
Abstract A plastic or resin product is obtained by mixing polyvinylpyrrolidone, modifiers and additives such as organic methacrylates, and crosslinking agents, and optionally catalysts, and causing polymerization to take place. The inventive product is insoluble in water but is hydratable with water, depending upon the proportions of the above mentioned components, and may take up in its structure as little as 5% by weight of water to as high as 90% by weight of water. The inventive hydrated product is optionally transparent, translucent, or opaque, and produced in any shape or size, depending only on the mold in which it is cast. The transparent product is especially suitable for contact lenses. The translucent and opaque products may be fabricated into membranes with pore sizes that can be made selectively, or cast into useful shapes and for other uses.
Inventors
- 👤 Maurice Seiderman
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 11:42
CPC Classifications
G; G02; G02B; G02B1/00; G02B1/04; G02B1/041; G02B1/043; C; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/12; C08F220/20; C08F26/00; C08F26/06; C08F271/00; C08F271/02
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
71 words
A contact lens comprising a hydrophilic polymer consisting essentially of a polymerized mixture of polyvinylpyrrolidone and a hydroxyalkyl methacrylate in a weight ratio to the polyvinylpyrrolidone of from 60:40 to about 99:1, from 0.1 to about 25 parts by weight for each 100 parts of the polyvinylpyrrolidone of a crosslinking agent, and an amount of catalyst ranging from zero to about five grams thereof for each 100 grams of reaction mixture.
Claim 2
Dependent Claim
71 words
A contact lens comprising a hydrophilic polymer consisting essentially of a polymerized mixture of polyvinylpyrrolidone and a hydroxyalkyl methacrylate in a weight ratio to the polyvinylpyrrolidone of from 60:40 to about 99:1, from 0.1 to about 25 parts by weight for each 100 parts of the polyvinylpyrrolidone of a crosslinking agent, and an amount of catalyst ranging from zero to about five grams thereof for each 100 grams of reaction mixture.
Claim 3
Dependent Claim
44 words
The contact lens of claim 1 wherein the crosslinking agent is selected from the group consisting of ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, 1,3-butylene glycol dimethacrylate, and methacrylic acid with N-methylol acrylamide.
Claim 4
Dependent Claim
39 words
The contact lens of claim 1 wherein the catalyst is present and is selected from the group consisting of benzoyl peroxide, lauryl peroxide, cumene hydroperoxide, dibutyl peroxide, azobisisobutyronitrile, tertiary butyl peroxide, tertiary butyl hydroperoxide, and ammonia plus hydrogen peroxide.
Claim 5
Dependent Claim
77 words
The contact lense of claim 1 wherein the crosslinking agent is selected from the group consisting of ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, 1,3-butylene glycol dimethacrylate, and methacrylic acid with N-methylol acrylamide and the catalyst is present and is selected from the group consisting of benzoyl peroxide, lauryl peroxide, cumene hydroperoxide, dibutyl peroxide, azobisisobuytronitrile, tertiary butyl peroxide, tertiary butyl hydroperoxide, and ammonia plus hydrogen peroxide.
Claim 6
Dependent Claim
16 words
The contact lens of claim 1 wherein the hydroxyalkyl methacrylate is hydroxyethyl methacrylate or hydroxypropyl methacrylate.
Claim 7
Dependent Claim
16 words
The contact lens of claim 2 wherein the hydroxyalkyl methacrylate is hydroxyethyl methacrylate or hydroxypropyl methacrylate.
Claim 8
Dependent Claim
16 words
The contact lens of claim 3 wherein the hydroxyalkyl methacrylate is hydroxyethyl methacrylate or hydroxypropyl methacrylate.
Claim 9
Dependent Claim
16 words
The contact lens of claim 4 wherein the hydroxyalkyl methacrylate is hydroxyethyl methacrylate or hydroxypropyl methacrylate.
Claim 10
Dependent Claim
29 words
The contact lens of claim 1 wherein the crosslinking agent is present in an amount ranging between 0.1 and 7 parts by weight per 100 parts of the polyvinylpyrrolidone.
Claim 11
Dependent Claim
29 words
The contact lens of claim 1 wherein the crosslinking agent is present in an amount ranging between 1 and 5 parts by weight per 100 parts of the polyvinylpyrrolidone.
Claim 12
Dependent Claim
150 words
A process of producing a substantially water insoluble resin which comprises the steps of mixing together polyvinylpyrrolidone and a hydroxyalkyl methacrylate in a weight ratio to the polyvinylpyrrolidone of from 60:40 to about 99:1; at least 0.1 part by weight for each 100 parts of the polyvinylpyrrolidone of a crosslinking agent selected from the group consisting of ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate 1,3-butylene glycol dimethacrylate, and methacrylic acid with N-methylolacrylamide; and an amount of catalyst ranging from 0 to about 5 grams thereof for each 100 grams of reaction mixture; and thereafter (a) heating the mixture thus formed to a temperature of at least about 50°C. and maintaining the reaction mixture at such temperature until polymerization is substantially completed, or (b) adding an accelerator to the reaction mixture and continuing the reaction until polymerization is substantially completed.
Claim 13
Dependent Claim
150 words
A process of producing a substantially water insoluble resin which comprises the steps of mixing together polyvinylpyrrolidone and a hydroxyalkyl methacrylate in a weight ratio to the polyvinylpyrrolidone of from 60:40 to about 99:1; at least 0.1 part by weight for each 100 parts of the polyvinylpyrrolidone of a crosslinking agent selected from the group consisting of ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate 1,3-butylene glycol dimethacrylate, and methacrylic acid with N-methylolacrylamide; and an amount of catalyst ranging from 0 to about 5 grams thereof for each 100 grams of reaction mixture; and thereafter (a) heating the mixture thus formed to a temperature of at least about 50°C. and maintaining the reaction mixture at such temperature until polymerization is substantially completed, or (b) adding an accelerator to the reaction mixture and continuing the reaction until polymerization is substantially completed.
Claim 14
Dependent Claim
59 words
A hydrophilic, substantially water insoluble polymer comprising a polymerized admixture of polyvinylpyrrolidone, an hydroxyalkyl methacrylate and a crosslinking agent, the weight ratio of said hydroxyalkyl methacrylate to said polyvinylpyrrolidone being from 60:40 to about 99:1, and the said crosslinking agent being present in an amount of at least 0.1 part by weight per 100 parts of the said polyvinylpyrrolidone.
Claim 15
Dependent Claim
59 words
A hydrophilic, substantially water insoluble polymer comprising a polymerized admixture of polyvinylpyrrolidone, an hydroxyalkyl methacrylate and a crosslinking agent, the weight ratio of said hydroxyalkyl methacrylate to said polyvinylpyrrolidone being from 60:40 to about 99:1, and the said crosslinking agent being present in an amount of at least 0.1 part by weight per 100 parts of the said polyvinylpyrrolidone.
References Cited (Backward Citations)
US3520949A
Cited
US3621079A
Cited
US3639524A
Cited
US3721657A
Cited
US3700761A
Cited
US3822196A
Cited
US3647736A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-06-29 | 1979-12-29 | 1980-06-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-06-29 | 1983-12-29 | 1984-06-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-06-29 | 1987-12-29 | 1988-06-29 | $7700.00 | Window Closed / Lapsed |