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US3955035A Expired / Lapsed US ⏱️ 0.0 years remaining

Transparent resin composite

Assignee: Topcon Corp
•
Filing: 1974-08-06
•
Granted: 1976-05-04
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Expires: 1994-08-06
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Abstract

Abstract Transparent resin composites comprising a substrate of a transparent plastic material coated with a cured film of at least one [(2,3-epoxypropoxy)alkyl]trialkoxysilane or of at least one [(2,3-epoxypropoxy)alkyl]trialkoxysilane and at least one transparent polymer compatible with said silane are provided. The resin composites have excellent abrasion resistance, surface hardness, heat resistance, chemical resistance, weathering resistance, etc. well retaining the transparency and other optical characteristics of the substrate resin. These resin composites can be used as transparent plastic panels, lenses, etc.

Inventors

  • 👤 Akihiko Ito
  • 👤 Isao Kaetsu
  • 👤 Hiroshi Okubo
  • 👤 Masamichi Kato
  • 👤 Koichiro Hayashi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 15:29
CPC Classifications
C; C09; C09D; C09D183/00; C09D183/04; C09D183/06; Y; Y10; Y10T; Y10T428/00; Y10T428/26; Y10T428/263; Y10T428/269; Y10T428/31504; Y10T428/31511; Y10T428/31652; Y10T428/31663; Y10T428/31667

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 52 words
A transparent resin composite comprising a substrate of a transparent plastic material coated with a cured film of at last one [(2,3-epoxypropoxy)alkyl]trialkoxysilane represented by the general formula: ##EQU2## whereby R is an alkylene group containing up to 4 carbon atoms and R' is an alkyl group containing up to 4 carbon atoms.
Claim 2
Dependent Claim 52 words
A transparent resin composite comprising a substrate of a transparent plastic material coated with a cured film of at last one [(2,3-epoxypropoxy)alkyl]trialkoxysilane represented by the general formula: ##EQU2## whereby R is an alkylene group containing up to 4 carbon atoms and R' is an alkyl group containing up to 4 carbon atoms.
Claim 3
Dependent Claim 87 words
The transparent resin composite as claimed in claim 1, wherein R of the general formula is one of methylene, ethylene and trimethylene and R' is one of methyl, ethyl, n-propyl and n-butyl; and the transparent plastic material is selected from a class consisting of poly(vinyl chloride) resin, poly(vinylidene chloride) resin, polycarbonate resin, poly(lower-alkyl acrylate) resins, poly(lower-alkyl methacrylate) resins, poly(diethyleneglycol bis(allyl carbonate)) resin, polystyrene resin, styrene-acrylonitrile copolymer resin, polyvinylbutyral resin, cellulose acetate resin, and polyester resin and the thickness of the cured coating film is 0.003 -2.0 mm.
Claim 4
Dependent Claim 73 words
The transparent resin composite as claimed in claim 2, wherein R of the general formula is one of trimethylene and ethylene, R' is one of methyl and ethyl, the transparent plastic material of the substrate is selected from a class consisting of polycarbonate resin poly(methyl acrylate) resin, poly(methyl methacrylate) resin, poly(ethyl acrylate) resin, poly(ethyl methacrylate) resin, poly(diethyleneglycol bis(allyl carbonate) resin, and the thickness of the cured coating film is 0.005 - 0.5 mm.
Claim 5
Dependent Claim 34 words
The transparent resin composite as claimed in claim 3, wherein R of the general formula is trimethylene and R' is methyl, and the thickness of the cured coating film is 0.01 - 0.2 mm.
Claim 6
Dependent Claim 66 words
A transparent resin composite comprising a substrate of a transparent plastic material coated with a cured film of at least one [(2,3-epoxypropoxy)alkyl]trialkoxysilane represented by the general formula: represented by the general formula: ##EQU3## whereby R is an alkylene group containing up to 4 carbon atoms and R' is an alkyl group containing up to 4 carbon atoms, and a transparent polymer which is compatible with [(2,3-epoxypropoxy)propyl]trialkoxysilanes.
Claim 7
Dependent Claim 66 words
A transparent resin composite comprising a substrate of a transparent plastic material coated with a cured film of at least one [(2,3-epoxypropoxy)alkyl]trialkoxysilane represented by the general formula: represented by the general formula: ##EQU3## whereby R is an alkylene group containing up to 4 carbon atoms and R' is an alkyl group containing up to 4 carbon atoms, and a transparent polymer which is compatible with [(2,3-epoxypropoxy)propyl]trialkoxysilanes.
Claim 8
Dependent Claim 111 words
The transparent composite resin material as claimed in claim 5, wherein R of the general formula is one of methylene, ethylene and trimethylene and R'is one of methyl, ethyl, n-propyl, and n-butyl; the transparent polymer compatible with [(2,3-epoxypropoxy)alkyl]trialkoxysilane is selected from a class consisting of polystyrene, poly(lower-alkyl acrylate), poly(lower-alkyl methacrylate), poly(gylcidyl methacrylate), cellulose nitrate, and cellulose acetate and the transparent plastic material of the substrate is selected from a class consisting of poly(vinyl chloride) resin, poly(lower-alkyl acrylate) resin, poly(lower-alkyl methacrylate) resin, poly(diethyleneglycol bis(allyl carbonate)) resin, polystyrene resin, styrene-acrylonitrile copolymer resin, polyvinylbutyral resin, cellulose acetate resin and polyester resin, and the thickness of the cured coating film is 0.003 - 2.0 mm.
Claim 9
Dependent Claim 96 words
The transparent composite resin material as claimed in claim 6, wherein R of the general formula is one of trimethylene and ethylene, R' is one of methyl and ethyl, the transparent polymer compatible with [(2,3-epoxypropoxy)alkyl]-trialkoxysilane is selected from a class consisting of poly(lower-alkyl acrylate), poly(lower-alkyl methacrylate), polystyrene and cellulose acetate, and the transparent plastic material of the substrate is selected from a class consisting of polycarbonate resin, poly(methyl acrylate) resin, poly(methyl methacrylate) resin, poly(ethyl acrylate) resin, poly(ethyl methacrylate) resin, poly(diethyleneglycol bis(allyl carbonate)) resin, and the thickness of the cured coating film is 0.005 - 0.5 mm.
Claim 10
Dependent Claim 35 words
The transparent composite resin material as claimed in claim 7, wherein R of the general formula is trimethylene and R' is methyl and the thickness of the cured coating film is 0.1 - 0.2 mm.

References Cited (Backward Citations)

US3451838A Cited
US3454454A Cited
US3650808A Cited
US3707397A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-05-04 1979-11-03 1980-05-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-05-04 1983-11-03 1984-05-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-05-04 1987-11-03 1988-05-04 $7700.00 Window Closed / Lapsed

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