US3948819A
Expired / Lapsed
US
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Cleaning composition
Assignee: 3M Co
•
Filing: 1973-06-18
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Granted: 1976-04-06
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Expires: 1993-06-18
Abstract
Abstract Cleaning compositions, having particular utility in cleaning aircraft, based on a synergistic combination of nonionic polyethoxylated surfactants. The inclusion of a fluoroaliphatic phosphate in the composition imparts resoilresistance to the cleaned surface.
Inventors
- 👤 Arthur G. Wilde
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 18:16
CPC Classifications
C; C11; C11D; C11D1/00; C11D1/004; C11D1/006; C11D1/66; C11D1/825; C11D1/72; C11D1/74
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
243 words
A cleaning composition having particular utility in the removal of soil from aluminum airplane surfaces and substantially preventing the redeposition thereon, consisting essentially of an aqueous solution, each liter thereof having dissolved therein 1. an effective amount for cleaning said airplane surfaces of at least 1 gram of a nonionic surfactant system consisting essentially of a. a first ethoxylated nonionic surfactant containing 35-55% oxyethylene units by weight, and b. a second ethoxylated nonionic surfactant containing at least 55% oxyethylene units by weight but not less than 10% more oxyethylene units by weight than does the first surfactant, said surfactants being selected from the group consisting of A. polyethoxylated alkyl phenols containing 8 to 12 carbon atoms in the alkyl group, polyethoxylated fatty acids of fatty acids containing about 18 carbon atoms, and polyethoxylated sorbitan esters of fatty acids wherein each fatty acid contains from 12 to 18 carbon atoms wherein the mol ratio of the first ethoxylated surfactant to the second ethoxylated surfactant is about 3.5:1 to 1:3, and B. ethoxylated C 11-15 secondary alkanols wherein the mol ratio of the first ethoxylated surfactant is about 4:1 to 1:3.5, and 2. in a concentration effective to substantially prevent redeposition of soil, at least 0.1 millimol per liter of a fluoroaliphatic phosphate selected from the group consisting of C.sub.8 F.sub.17 SO.sub.2 N(C.sub.2 H.sub.5)C.sub.2 H.sub.4 OPO(OH).sub.2 [cf.sub.3 (cf.sub.2).sub.7 so.sub.2 n(c.sub.2 h.sub.5)c.sub.2 h.sub.4 o]po(onh.sub.4), and [CF.sub.3 (CF.sub.2).sub.5-14 C.sub.2 H.sub.4 O].sub.2 PO[ONH.sub.2 (C.sub.2 H.sub.4 OH).sub.2 ] .
Claim 2
Dependent Claim
243 words
A cleaning composition having particular utility in the removal of soil from aluminum airplane surfaces and substantially preventing the redeposition thereon, consisting essentially of an aqueous solution, each liter thereof having dissolved therein 1. an effective amount for cleaning said airplane surfaces of at least 1 gram of a nonionic surfactant system consisting essentially of a. a first ethoxylated nonionic surfactant containing 35-55% oxyethylene units by weight, and b. a second ethoxylated nonionic surfactant containing at least 55% oxyethylene units by weight but not less than 10% more oxyethylene units by weight than does the first surfactant, said surfactants being selected from the group consisting of A. polyethoxylated alkyl phenols containing 8 to 12 carbon atoms in the alkyl group, polyethoxylated fatty acids of fatty acids containing about 18 carbon atoms, and polyethoxylated sorbitan esters of fatty acids wherein each fatty acid contains from 12 to 18 carbon atoms wherein the mol ratio of the first ethoxylated surfactant to the second ethoxylated surfactant is about 3.5:1 to 1:3, and B. ethoxylated C 11-15 secondary alkanols wherein the mol ratio of the first ethoxylated surfactant is about 4:1 to 1:3.5, and 2. in a concentration effective to substantially prevent redeposition of soil, at least 0.1 millimol per liter of a fluoroaliphatic phosphate selected from the group consisting of C.sub.8 F.sub.17 SO.sub.2 N(C.sub.2 H.sub.5)C.sub.2 H.sub.4 OPO(OH).sub.2 [cf.sub.3 (cf.sub.2).sub.7 so.sub.2 n(c.sub.2 h.sub.5)c.sub.2 h.sub.4 o]po(onh.sub.4), and [CF.sub.3 (CF.sub.2).sub.5-14 C.sub.2 H.sub.4 O].sub.2 PO[ONH.sub.2 (C.sub.2 H.sub.4 OH).sub.2 ] .
Claim 3
Dependent Claim
19 words
The cleaning composition of claim 1 further including sufficient potassium carbonate to make the pH of said solution 9-10.8.
Claim 4
Dependent Claim
131 words
A cleaning composition having particular utility in the removal of soil from aluminum airplane surfaces, consisting essentially of an aqueous solution, each liter thereof having dissolved therein, in a concentration effective for cleaning said airplane surfaces, at least 1 gram of a nonionic surfactant system consisting essentially of a. a first ethoxylated C 11-15 secondary alkanol nonionic surfactant containing 35-55% oxyethylene units by weight, and b. a second ethoxylated C 11-15 secondary alkanol nonionic surfactant containing at least 55% oxyethylene units by weight but not less than 10% more oxyethylene units by weight than does the first surfactant, wherein the mol ratio of the first ethoxylated alkanol surfactant to the second ethoxylated alkanol surfactant is about 4:1 to 1:3.5, and sufficient potassium carbonate to make the pH of said solution 9-10.8.
Claim 5
Dependent Claim
131 words
A cleaning composition having particular utility in the removal of soil from aluminum airplane surfaces, consisting essentially of an aqueous solution, each liter thereof having dissolved therein, in a concentration effective for cleaning said airplane surfaces, at least 1 gram of a nonionic surfactant system consisting essentially of a. a first ethoxylated C 11-15 secondary alkanol nonionic surfactant containing 35-55% oxyethylene units by weight, and b. a second ethoxylated C 11-15 secondary alkanol nonionic surfactant containing at least 55% oxyethylene units by weight but not less than 10% more oxyethylene units by weight than does the first surfactant, wherein the mol ratio of the first ethoxylated alkanol surfactant to the second ethoxylated alkanol surfactant is about 4:1 to 1:3.5, and sufficient potassium carbonate to make the pH of said solution 9-10.8.
Claim 6
Dependent Claim
59 words
The cleaning composition of claim 3 further including, in a concentration effective to substantially prevent redeposition of soil, at least 0.1 millimol per liter of a fluoroaliphatic phosphate selected from the group consisting of C.sub.8 F.sub.17 SO.sub.2 N(C.sub.2 H.sub.5)C.sub.2 H.sub.4 OPO(OH).sub.2, [cf.sub.3 (ch.sub.2).sub.5-14 c.sub.2 h.sub.4 o]po[onh.sub.2 (c.sub.2 h.sub.4 oh).sub.2 ] and [CF.sub.3 (CF.sub.2).sub.7 SO.sub.2 N(C.sub.2 H.sub.5)C.sub.2 H.sub.4 O].sub.2 PO(ONH.sub.2).
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-04-06 | 1979-10-06 | 1980-04-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-04-06 | 1983-10-06 | 1984-04-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-04-06 | 1987-10-06 | 1988-04-06 | $7700.00 | Window Closed / Lapsed |