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US3899491A Expired / Lapsed US ⏱️ 0.0 years remaining

Alkyl alkanoate derivatives of substituted piperazines and polymer compositions stabilized thereby

Assignee: Novartis Corp
•
Filing: 1973-02-15
•
Granted: 1975-08-12
•
Expires: 1993-02-15
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Abstract

Abstract Alkyl alkanoate derivatives of substituted piperazines are stabilizers for synthetic polymeric materials normally subject to deterioration caused by ultraviolet light. The compounds may be formed by reacting a substituted piperazine with an acrylate or reacting a substituted piperazine with an Alpha -haloalkanoate. Polymeric compositions containing these stabilizers may also contain a hindered phenolic compound. A typical embodiment is noctadecyl- Beta -(15( 7,15diazadispiro(5,1,5,3)hexadecane)propionate.

Inventors

  • 👤 Chester E Ramey
  • 👤 John J Luzzi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 16:29
CPC Classifications
C; C07; C07D; C07D295/00; C07D295/02; C07D295/027; C07D295/04; C07D295/14; C07D295/145; C07D295/15; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3442; C08K5/3462

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 5 words
A COMPOUND OF THE FORMULA
Claim 2
Dependent Claim 5 words
A COMPOUND OF THE FORMULA
Claim 3
Dependent Claim 9 words
A compound according to claim 1 having the formula
Claim 4
Dependent Claim 14 words
A compound according to claim 2, wherein R4 is hydrogen and m is 0.
Claim 5
Dependent Claim 31 words
A compound according to claim 1, wherein R1 and R2 are methyl; R3 is alkyl of from 1 to 20 carbon atoms; R4 is hydrogen and m is 0 or 1.
Claim 6
Dependent Claim 14 words
A compound according to claim 4, wherein R4 is hydrogen and m is 0.
Claim 7
Dependent Claim 13 words
A compound according to claim 1, which is methyl- Beta -(15( 7,15-diazadispiro(5,1,5,3)hexadecane)) propionate.
Claim 8
Dependent Claim 12 words
A compound according to claim 1, which is methyl- Beta -(4( 2,2,6,6-tetramethylpiperazino)propionate.
Claim 9
Dependent Claim 13 words
A compound according to claim 1, which is n-dodecyl- Beta -(15( 7,15-diazadispiro(5,1,5,3)hexadecane)) propionate.
Claim 10
Dependent Claim 13 words
A compound according to claim 1, which is n-octadecyl- Beta -(15( 7,15-diazadispiro(5,1,5,3)hexadecane)) propionate.
Claim 11
Dependent Claim 14 words
A compound according to claim 1, which is methyl- Beta -(15( 7,15-diazadispiro(5,1,5,3)hexadecane)) Alpha -methylpropionate.
Claim 12
Dependent Claim 11 words
A compound according to claim 1, which is methyl Alpha -(4-(2,2,6,6-tetramethylpiperazine))acetate.
Claim 13
Dependent Claim 11 words
A commpound according to claim 1, which is ethyl- Alpha -(4-(2,2,6,6-tetramethylpiperazino))propionate.
Claim 14
Dependent Claim 12 words
A compound according to claim 1, which is n-octadecyl- Alpha -(4-(2,2,6,6-tetramethylpiperazino)) acetate.
Claim 15
Dependent Claim 13 words
A compound according to claim 1, which is n-dodecyl- Alpha -(15( 7,15-diazadispiro(5,1,5,3)hexadecane)) propionate.
Claim 16
Dependent Claim 12 words
A compound according to claim 1, which is n-lauryl- Beta -(4( 2,2,6,6-tetramethylpiperazino))propionate.

References Cited (Backward Citations)

US3318876A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-08-11 1979-02-10 1979-08-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-08-11 1983-02-10 1983-08-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-08-11 1987-02-10 1987-08-12 $7700.00 Window Closed / Lapsed

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