US3857809A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polyurethane-ureas based on cis-trans-1,4-diaminocyclohexane
Assignee: Bayer AG
•
Filing: 1973-04-23
•
Granted: 1974-12-31
•
Expires: 1993-04-23
Abstract
Abstract Light stable polyurethane coatings with a considerably increased softening range and melting points coupled with improved resistance to perchlorethylene is obtained by using a chain extender comprising at least 80 mol % 1,4-diamino cyclohexane with a cis/transisomer ratio of from 10/90 to 60/40.
Inventors
- 👤 W Thoma
- 👤 K Noll
- 👤 H Oertel
- 👤 B Zorn
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 07:36
CPC Classifications
D; D06; D06N; D06N3/00; D06N3/12; D06N3/14; C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/0838; C08G18/0842; C08G18/0847; C08G18/0852; C08G18/10; C08G18/70; C08G18/72; C08G18/73; C08G18/74; C08G18/75; C14; C14C; C14C11/00; C14C11/003; C14C11/006; D06M; D06M15/00; D06M15/19; D06M15/37; D06M15/564
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
88 words
A POLYURETHANE POLYUREA PREPARED BY A PROCESS WHICH COMPRISES, REACTING IN AN INERT ORGANIC SOLVENT A A. CHAIN EXTENDER COMPRISING AT LEAST 80 MOL % 1,4-DIAMINO CYCLOHEXANE WITH A CIS/TRANSISOMER RATIO OF FROM 10/90 TO 60/40, WITH B. AN ISOCYANTO TERMINATED PREPOLYMER PREPARED BY A PROCESS WHICH COMPRISES REACTING I. SUBSTANTIALLY LINEAR POLYHYDROXY COMPOUNDS WITH MOLECULAR WEIGHTS OF FROM 500 TO 5000, WITH II. ALIPHATIC OR CYCLOALIPHTIC DIISOCYANATE THE MOLAR RATIO OF HYDROXY GROUPS TO ISOCYANATE GROUPS BEING BETWEEN ABOUT 1:1.5 AND 1: 5, AND EVAPORATING THE SOLVENT.
Claim 2
Dependent Claim
88 words
A POLYURETHANE POLYUREA PREPARED BY A PROCESS WHICH COMPRISES, REACTING IN AN INERT ORGANIC SOLVENT A A. CHAIN EXTENDER COMPRISING AT LEAST 80 MOL % 1,4-DIAMINO CYCLOHEXANE WITH A CIS/TRANSISOMER RATIO OF FROM 10/90 TO 60/40, WITH B. AN ISOCYANTO TERMINATED PREPOLYMER PREPARED BY A PROCESS WHICH COMPRISES REACTING I. SUBSTANTIALLY LINEAR POLYHYDROXY COMPOUNDS WITH MOLECULAR WEIGHTS OF FROM 500 TO 5000, WITH II. ALIPHATIC OR CYCLOALIPHTIC DIISOCYANATE THE MOLAR RATIO OF HYDROXY GROUPS TO ISOCYANATE GROUPS BEING BETWEEN ABOUT 1:1.5 AND 1: 5, AND EVAPORATING THE SOLVENT.
Claim 3
Dependent Claim
27 words
The product of claim 1 wherein the solvent used is a mixture of an aromatic hydrocarbon, or chlorinated aliphatic hydrocarbon, with primary secondary or tertiary aliphatic alcohols.
Claim 4
Dependent Claim
27 words
A product according to claim 1 wherein the isocyanato terminated prepolymers are prepared from substantially linear polyhydroxyl compounds with molecular weights of from about 62 to 400.
Claim 5
Dependent Claim
22 words
The product of claim 1 wherein the prepolymers, diamines and chain extenders are reacted in a solvent mixture of chlorinated aromatic hydrocarbons.
Claim 6
Dependent Claim
15 words
The product of claim 1 wherein the polyhydroxyl compounds are dihydroxy polyesters, polycarbonates or polyacetones.
Claim 7
Dependent Claim
15 words
The product of claim 1 wherein the prepolymer includes diols with a tertiary amino group.
Claim 8
Dependent Claim
20 words
The product of claim 1 wherein the diisocyanate mixture contains at least 75 mol % of 1-isocyanato-3-isocyanato methyl-3, 5,5-trimethyl cyclohexane.
Claim 9
Dependent Claim
29 words
The product of claim 1 wherein the molar ratio of isocyanate groups to amine groups in the chain extending reaction is between 1 : 1.0 and 1 : 1.15.
Claim 10
Dependent Claim
28 words
The product of claim 1 wherein polyhydroxyl compound has a molecular weight of from 800 to 3000 and a melting point below 45*C by the Kofler Bench method.
Claim 11
Dependent Claim
29 words
The product of claim 1 wherein the prepolymer includes a dihydroxy polyester selected from the group adipic acid-ethylene glycol, -1,6-hexane diol, -2,2-dimethyl propane diol, -1,4-butane diol or -1,2-propane diol.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1977-12-30 | 1978-07-01 | 1978-12-31 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1981-12-30 | 1982-07-01 | 1982-12-31 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1985-12-30 | 1986-07-01 | 1986-12-31 | $7700.00 | Window Closed / Lapsed |