← Back to Patent Explorer
US3854946A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for chemically bonding a dyestuff to a polymeric substrate

Assignee: Pharmacia and Upjohn Co
•
Filing: 1973-09-14
•
Granted: 1974-12-17
•
Expires: 1993-09-14
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Radiation (thermal and light)-sensitive polymers are provided which are characterized by the recurring unit of the formula: WHEREIN R'' is lower-alkoxy or phenyl; one of R2 and R3 is hydrogen and the other is WHEREIN A alkylene from 2 to 10 carbon atoms having 2 to 6 carbon atoms between valencies, R'''' lower-alkyl or halogen, x is 1 to 2, y is 0 to 2, and x + y 1 to 3. Water soluble salts also disclosed. The polymers are useful for chemically bonding basic dyestuffs to non-dyereceptive substrates (e.g. polyethylene) by coating the substrate with radiation sensitive polymer and exposing the coated substrate to irradiation. The treated substrate is then contacted with a basic dyestuff which bonds thereto via the free carboxylic groups in the coating. The irradiation can be carried out imagewise to produce an appropriate image on the substrate which image is developed by dissolving out unexposed radiation-sensitive polymer prior to application of the dye. Bonding of the radiation-sensitive polymers of the invention to substrates in the above manner can also be employed as a means of rendering hydrophilic a variety of substrates which are hydrophobic.

Inventors

  • 👤 H Ulrich
  • 👤 A Sayigh
  • 👤 F Stuber

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 09:29
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/008; G03F7/012; C; C08; C08F; C08F8/00; C08F8/34; D; D06; D06P; D06P1/00; D06P1/44; D06P1/64; D06P1/642; D06P1/6423; D06P5/00; D06P5/22; Y; Y10; Y10S; Y10S522/00; Y10S522/904

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 42 words
A PROCESS FOR CHEMICALLY BONDING A BASIC DYE TO A SUBSTRATE CONTAINING A PLURALITY OF C-H BONDS SUBSTRATE IS NOT NORMALLY RECEPTIVE TO DYESTUFFS WHICH PROCESS COMPRISES: A. APPLYING TO THE SAID SUBSTRATE A RADIATION SENSITIVE POLYMER CHARACTERIZED BY THE RECURRING UNIT:
Claim 2
Dependent Claim 42 words
A PROCESS FOR CHEMICALLY BONDING A BASIC DYE TO A SUBSTRATE CONTAINING A PLURALITY OF C-H BONDS SUBSTRATE IS NOT NORMALLY RECEPTIVE TO DYESTUFFS WHICH PROCESS COMPRISES: A. APPLYING TO THE SAID SUBSTRATE A RADIATION SENSITIVE POLYMER CHARACTERIZED BY THE RECURRING UNIT:
Claim 3
Dependent Claim 39 words
A process according to claim 1, wherein in step (b) the treated substrate is exposed to radiation in selected areas only and the unexposed light- and heat-sensitive polymer is removed from the combination prior to carrying out step (c).
Claim 4
Dependent Claim 30 words
A process according to claim 2 wherein the removal of the unexposed light- and heat-sensitive polymer is accomplished by dissolving said unexposed polymer in an aqueous solution of a base.
Claim 5
Dependent Claim 62 words
A process according to claim 2 wherein sufficient of the free carboxylic acid groups in the starting light- and heat-sensitive polymer have been converted to the corresponding salt to render said polymer water-soluble prior to its application to the substrate, and, after the irradiation step is complete, the unexposed light- and heat-sensitive polymer is removed from the combination by washing with water.
Claim 6
Dependent Claim 17 words
A process according to claim 1 wherein the substrate not normally receptive to dyestuffs is a polyolefin.
Claim 7
Dependent Claim 22 words
A process according to claim 1 wherein the light- and heat sensitive polymer has a recurring unit having a formula selected from:
Claim 8
Dependent Claim 47 words
A process for chemically bonding a dyestuff to a polymeric substrate which contains a plurality of C-H bonds and is not normally receptive to said dyestuff which process comprises: a. applying to said substrate a coating of a light- and heat-sensitive polymer characterized by the recurring unit:
Claim 9
Dependent Claim 47 words
A process for chemically bonding a dyestuff to a polymeric substrate which contains a plurality of C-H bonds and is not normally receptive to said dyestuff which process comprises: a. applying to said substrate a coating of a light- and heat-sensitive polymer characterized by the recurring unit:
Claim 10
Dependent Claim 34 words
The process of claim 7 wherein the irradiation in step (b) is carried out imagewise and, after said exposure, the image is developed by dissolving out the unexposed coating of light- and heat-sensitive polymer.
Claim 11
Dependent Claim 31 words
The process of claim 8 wherein the removal of the unexposed coating of light- and heat-sensitive polymer is accomplished by dissolving said unexposed coating in an aqueous solution of a base.
Claim 12
Dependent Claim 62 words
A process according to cLaim 8 wherein sufficient of the free carboxylic acid groups in the starting light- and heat-sensitive polymer have been converted to the corresponding salt to render said polymer water-soluble prior to its application to the substrate, and, after the irradiation step is complete, the unexposed light- and heat-sensitive polymer is removed from the combination by washing with water.
Claim 13
Dependent Claim 11 words
The process of claim 7 wherein the polymeric substrate is polyolefin.
Claim 14
Dependent Claim 16 words
The process of claim 7 wherein the polyolefinic substrate is in the form of a film.

References Cited (Backward Citations)

US2948610A Cited
US3467518A Cited
US3462268A Cited
US3734844A Cited
US3699080A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-12-16 1978-06-17 1978-12-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-12-16 1982-06-17 1982-12-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-12-16 1986-06-17 1986-12-17 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag