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US3768976A Expired / Lapsed US ⏱️ 0.0 years remaining

Temperature-time integrating indicator

Assignee: United States Department of the Army
•
Filing: 1971-05-20
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Granted: 1973-10-30
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Expires: 1991-05-20
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Abstract

Abstract A temperature-time integrating indicator for determining the safe limit of storage of a food product or other material which is subject to deterioration due to temperature and length of storage. In its preferred form the temperature-time integrating indicator comprises a transparent polymeric film package containing a warning message enclosed in the package together with an aqueous solution of a redox dye, e.g., sodium anthraquinone beta-sulfonate. The dye is in its reduced state, which is dark red and obscures the warning message. The rate of permeation of oxygen into the package is a function of the temperature at which the package is exposed to the atmospheric environment. When sufficient time has elapsed at temperatures which may vary, the due becomes oxidized, turning colorless and revealing the warning message. The effects of temperature and time on the migration of oxygen through the polymeric film followed by reaction of the oxygen with the redox dye in the solution are integrated. This is related to product deterioration in storage, since the rate of this deterioration also depends on the temperature history and the time of storage. The use or disposal of stored foods and the like may be scheduled in accordance with warnings provided by the temperature-time integrating indicators.

Inventors

  • 👤 K Hu
  • 👤 J Loconti

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 13:29
CPC Classifications
G; G01; G01K; G01K3/00; G01K3/02; G01K3/04; G09; G09F; G09F3/00; G09F3/02; G09F3/0291

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 51 words
A temperature-time integrating indicator as in claim 1, wherein said legibility-controlling means in the reduced state is sufficiently opaque to prevent legibility of said message-conveying means through said transparent portion, but in the substantially completely oxidized state becomes sufficiently transparent to provide legibility of said message-conveying means through said transparent portion.
Claim 2
Dependent Claim 51 words
A temperature-time integrating indicator as in claim 1, wherein said legibility-controlling means in the reduced state is sufficiently transparent to provide legibility of said message-conveying means through said transparent portion, but in the substantially completely oxidized state becomes sufficiently opaque to prevent legibility of said message-conveying means through said transparent portion.
Claim 3
Dependent Claim 41 words
A temperature-time integrating indicator as in claim 2, wherein said legibility-controlling means comprises a redox dye in its reduced state and a solution capable of absorbing oxygen which permeates said container and of oxidizing said redox dye to its oxidized state.
Claim 4
Dependent Claim 31 words
A temperature-time integrating indicator as in claim 4, wherein said solution comprises sufficient zinc in aqueous alkali to maintain said redox dye in its reduced state for a predetermined temperature-time combination.
Claim 5
Dependent Claim 16 words
A temperature-time integrating indicator as in claim 4, wherein said redox dye is sodium anthraquinone beta-sulfonate.
Claim 6
Dependent Claim 35 words
A temperature-time integrating indicator as in claim 2, wherein said legibility-controlling means comprises metallic copper and a solution capable of absorbing oxygen which permeates said container and of oxidizing said copper to its oxidized state.
Claim 7
Dependent Claim 36 words
A temperature-time integrating indicator as in claim 7, wherein said solution comprises sufficient ammonia to convert substantially all of said metallic copper into soluble copper-ammonia complexes under the influence of said oxygen which permeates said container.
Claim 8
Dependent Claim 31 words
A temperature-time integrating indicator as in claim 3, wherein said legibility-controlling means consists essentially of a transparent self-supporting methyl cellulose film containing ferrous chloride and phosphoric acid dispersed throughout said film.

References Cited (Backward Citations)

US3018611A Cited
US3065083A Cited
US3000706A Cited
US3243303A Cited
US3480402A Cited
US3520124A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-10-29 1977-04-30 1977-10-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-10-29 1981-04-30 1981-10-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-10-29 1985-04-30 1985-10-30 $7700.00 Window Closed / Lapsed

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