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US3723569A Expired / Lapsed US ⏱️ 0.0 years remaining

Blends of copolyesters with cured epoxy resins

Assignee: EIDP Inc
•
Filing: 1972-03-20
•
Granted: 1973-03-27
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Expires: 1992-03-20
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Abstract

Abstract An improved usually thermosetting copolyester composition comprising: A. AT LEAST ONE SEGMENTED COPOLYESTER POLYMER CONSISTING ESSENTIALLY OF (1) ABOUT 5-85 WEIGHT PERCENT OF RECURRING LONG CHAIN ESTER UNITS DERIVED FROM AT LEAST ONE DICARBOXYLIC ACID HAVING A MOLECULAR WEIGHT BELOW ABOUT 300 AND AT LEAST ONE POLY- (ALKYLENE OXIDE) GLYCOL HAVING A MOLECULAR WEIGHT BETWEEN ABOUT 400-6,000 AND A CARBON-TO-OXYGEN RATIO OF ABOUT 2.0-4.3 AND (2) ABOUT 15-95 WEIGHT PERCENT OF SHORT CHAIN ESTER UNITS WHICH ARE DERIVED FROM AT LEAST ONE LOW MOLECULAR WEIGHT DIOL HAVING A MOLECULAR WEIGHT OF LESS THAN ABOUT 250 AND AT LEAST ONE LOW MOLECULAR WEIGHT DICARBOXYLIC ACID HAVING A MOLECULAR WEIGHT OF LESS THAN ABOUT 300, B. ABOUT 1.0 TO 50 PERCENT BY WEIGHT BASED ON SAID COPOLYESTER, OF A POLYEPOXIDE HAVING A FUNCTIONALITY OF AT LEAST TWO AND C. ABOUT 0.5 TO 1.1 EQUIVALENTS, PER EPOXY EQUIVALENT, OF AN EPOXY CURING AGENT SELECTED FROM AROMATIC AND ALIPHATIC POLYAMINES AND CYCLIC ANHYDRIDES OF POLYCARBOXYLIC ACIDS. Optionally from 0.05 to 0.5 weight percent based on said copolyester of an epoxy catalyst may be included in the composition.

Inventors

  • 👤 G Hoeschele

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 19:45
CPC Classifications
C; C08; C08L; C08L63/00; C08G; C08G63/00; C08G63/66; C08G63/668; C08G63/672; C08L67/00; C08L67/02; C08L67/025

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 20 words
The composition of claim 1 wherein the curing agent is a polyamine having at least two aromatic primary amine groups.
Claim 2
Dependent Claim 25 words
The composition of claim 2 wherein said curing agent is selected from the group consisting of m-phenylene diamine, 4,4''-diamino diphenylmethane, cumene diamine and mixtures thereof.
Claim 3
Dependent Claim 28 words
The composition of claim 1 wherein said curing agent is a cyclic anhydride of a carboxylic acid which has at least one structural unit represented by the formula:
Claim 4
Dependent Claim 22 words
The composition of claim 1 wherein the polyepoxide has an epoxide equivalent of about 50-2,000 and is represented by the general formula:
Claim 5
Dependent Claim 16 words
The composition of claim 5 wherein R'''' contains carbocyclic aromatic nuclei substituted with Cl or Br.
Claim 6
Dependent Claim 26 words
The composition of claim 5 wherein R'''''' and R'''''''' are hydrogen, n is 2 to 10 and the polyepoxide has an epoxide equivalent of about 75-1,000.
Claim 7
Dependent Claim 12 words
The composition of claim 5 wherein said polyepoxide is a polyglycidyl compound.
Claim 8
Dependent Claim 23 words
The composition of claim 1 wherein said copolyester also contains 0.05-0.5 weight percent, based on the weight of copolyester, of an epoxy catalyst.
Claim 9
Dependent Claim 14 words
The composition of claim 9 wherein said epoxy catalyst is a secondary aliphatic amine.
Claim 10
Dependent Claim 27 words
The composition of claim 1 wherein said dicarboxylic acid is selected from the group consisting of phthalic acid, terephahalic acid, isophthalic acid, their esters and mixtures thereof.
Claim 11
Dependent Claim 21 words
The composition of claim 2 wherein the poly(alkylene oxide) glycol is poly(tetramethylene oxide) glycol having a molecular weight of about 600-2,000.
Claim 12
Dependent Claim 30 words
The composition of claim 2 wherein said glycol is poly(tetramethylene oxide) glycol having a molecular weight of about 600-2,000, said dicarboxylic acid is dimethyl terephthalate and said diol is 1,4-butanediol.
Claim 13
Dependent Claim 30 words
The composition of claim 2 wherein said dicarboxylic acid is a mixture of dimethyl terephthalate and a maximum of 30 mole percent of dimethyl isophthalate, dimethyl phthalate or mixtures thereof.
Claim 14
Dependent Claim 15 words
The composition of claim 1 wherein said polyepoxide is a diglycidyl ether of bisphenol A.
Claim 15
Dependent Claim 16 words
The composition of claim 1 wherein said polyepoxide is a polyglycidyl ether of a phenol-formaldehyde novolac.

References Cited (Backward Citations)

US2935488A Cited
US2890196A Cited
US2890197A Cited
GB872254A Cited
US3297782A Cited
US3397254A Cited
US3378497A Cited
US3670045A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-03-26 1976-09-25 1977-03-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-03-26 1980-09-25 1981-03-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-03-26 1984-09-25 1985-03-27 $7700.00 Window Closed / Lapsed

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