← Back to Patent Explorer
US3647535A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of controllably oxidizing a silicon wafer

Assignee: NCR Voyix Corp
•
Filing: 1969-10-27
•
Granted: 1972-03-07
•
Expires: 1989-10-27
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract The present invention relates to a method of growing an optimumthickness silicon dioxide layer for a nonvolatile metal-silicon nitride-silicon oxide-silicon field effect memory transistor near atmospheric pressure in a controllable manner. A silicon wafer, having source and drain regions therein, is placed within an epitaxial reactor through which an inert gas is then made to flow at a rate of 30 liters/minute. The silicon wafer is heated to 1,000* centigrade, and a 1.2-liter flow of oxygen is introduced into said epitaxial reactor for 15 minutes. The flow of oxygen gas is dispersed throughout the flow of the inert gas. The silicon crystal is slowly oxidized to form a 52.5-angstrom thick silicon dioxide layer thereon. When the selected time of oxidation has passed, the small flow of the oxygen into the epitaxial reactor is stopped. The total oxygen-inert flowing gas pressure in the epitaxial reactor is slightly above atmospheric pressure. A precise regulation of the thickness of a silicon dioxide layer grown on a silicon crystal is achieved by regulating the flow rate of oxygen relative to the flow rate of inert gas and regulating the oxidation temperature. The method of the present invention allows one to produce a 52.5-angstrom thick silicon dioxide layer on a silicon crystal. The 52.5-angstrom thick silicon dioxide layer is then covered with a 1,000-angstrom thick silicon nitride layer by chemical decomposition in the epitaxial reactor. A metal electrode in the silicon nitride layer and metal electrodes on the uncovered source and drain regions complete an MNOS field effect memory transistor which has very good switching characteristics.

Inventors

  • 👤 Charles T Naber

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 04:56
CPC Classifications
H; H10; H10D; H10D30/00; H10D30/60; H10D30/69; C; C23; C23C; C23C8/00; C23C8/06; C23C8/08; C23C8/10; C23C8/12; H10D64/00; H10D64/01; H10D64/013; H10D64/01302; H10D64/01332; H10D64/01336; H10D99/00; H10P; H10P14/00; H10P14/60; H10P14/66; H10P14/662; H10P14/668; H10P14/6681; H10P14/6682; H10P14/69; H10P14/694; H10P14/6943; H10P14/69433; H10P14/63; H10P14/6302; H10P14/6304; H10P14/6306; H10P14/6308; H10P14/6309; H10P14/6322; H10P14/6326; H10P14/6328; H10P14/6334; H10P14/692; H10P14/6921; H10P14/69215; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 140 words
A method of controllably growing an oxide layer of a desired small thickness upon a silicon wafer, comprising: a. passing an inert gas through an oxidation container and over said silicon wafer to flush oxygen from said oxidation container; b. heating said silicon wafer in said flushed oxygen-free container to a selected temperature; c. simultaneously passing a mixture of an oxidizing gas at a first selected flow rate and an inert gas at a second flow rate selected in relation to said first flow rate, through said oxidation container and over said silicon wafer, for a selected period of time, so as to slowly grow an oxide layer of a desired small thickness on said silicon wafer; and d. stopping the flow of said oxidizing gas after said selected period of time while continuing the flow of said inert gas.
Claim 2
Independent Claim 140 words
A method of controllably growing a less than 200-angstrom thick silicon dixode layer upon a silicon wafer, comprising: a. passing an inert gas through an oxidation container and over said silicon wafer to flush oxygen from said oxidation container; b. heating said silicon wafer in said flushed oxygen-free container to a temperature of approximately 1,000* centigrade; c. simultaneously passing a mixture of oxygen gas at a first selected flow rate, and an inert gas at a second flow rate selected in relation to said first flow rate through said oxidation container for a period of approximately 20 minutes, so as to grow a silicon dioxide layer of less than a 200 angstrom thickness on the silicon wafer; and d. stopping the flow of said oxygen gas after said selected period of time while continuing the flow of said inert gas.
Claim 3
Independent Claim 112 words
A method of controllably growing a silicon dioxide layer less than 200 angstroms upon a silicon wafer, comprising a. heating said silicon wafer to a temperature between 700* and 1,100* centigrade within a flushed oxygen-free oxidation container, b. simultaneously passing a mixture of an oxidizing gas at a first flow rate between 0 and 100 liters per minute and an inert gas at a second flow rate between 0 and 100 liters per minute through said flushed oxygen-free oxidation container for a period of time less than 60 minutes; and c. stopping the flow of said oxidizing gas after said selected period of time while continuing the flow of said inert gas.
Claim 4
Independent Claim 111 words
A method of controllably growing an approximately 50-angstrom thick silicon dioxide layer upon a silicon wafer, comprising: a. heating said silicon wafer in a flushed oxygen-free oxidation container to a temperature of approximately 1,000* centigrade; b. simultaneously passing a mixture of a flowing oxygen gas and a flowing inert gas through said oxidation container and over said silicon wafer for a concurrent period of approximately 15 minutes, the flow rate of the oxygen gas being approximately 4 percent of the total flow rate of the two flowing gases; and c. stopping the flow of said oxidizing gas after said selected period of time while continuing the flow of said inert gas.
Claim 5
Dependent Claim 14 words
The method of claim 5 wherein the oxidation container is an epitaxial reactor one.
Claim 6
Independent Claim 222 words
A method of making a nonvolatile metal-silicon nitride-silicon oxide-silicon field effect memory transistor whose threshold voltage is easily varied by means of a switching voltage, comprising: a. heating a silicon wafer of a first conductivity type, having source and drain regions of a second conductivity type, in a flushed oxygen-free oxidation container to a temperature of approximately 1,000* centigrade; b. simultaneously passing flowing oxygen gas, along with flowing inert gas, through said oxidation container and over said silicon wafer for a period of approximately 15 minutes, the oxygen flow rate being approximately 4 percent of the total flow rate of the two flowing gases to controllably grow an approximately 50-angstrom thick silicon dioxide layer on the silicon wafer; c. stopping the flow of said oxygen gas while continuing the flow of said inert gas; d. passing silicon-nitride-forming gases through said oxidation container to form an approximately 1,000-angstrom thick silicon nitride layer on the silicon dioxide layer; e. cooling the silicon wafer; f. stopping the flow of said inert gas; g. etching the silicon dioxide and silicon nitride layers off of the source and drain regions; and h. evaporating a gate electrode on the silicon nitride layer, a source electrode on said source region, and a drain electrode on said drain region, to form a nonvolatile metal-silicon nitride-silicon oxide-silicon field effect memory transistor.

References Cited (Backward Citations)

US3158505A Cited
US3385729A Cited
US3426422A Cited
US3460003A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-03-07 1975-09-06 1976-03-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-03-07 1979-09-06 1980-03-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-03-07 1983-09-06 1984-03-07 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag