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EP0475620A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Microemulsion diesel fuel compositions and method of use

Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1991-08-23
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Granted: —
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Expires: 2011-08-23
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Abstract

Abstract The present invention relates to translucent and thermodynamically stable fuel compositions having improved combustion efficiency and reduced smoke, particulate, CO, and NOx emissions. The fuel compositions comprise, for example, a diesel fuel, water, or an aqueous solution of a low molecular weight alcohol and/or a water-soluble reagent, and a surfactant system which comprises a balanced blend of one or more hydrophilic surfactants and one or more lipophilic surfactants, wherein the diesel fuel composition can contain as high as 30 weight percent of aqueous phase with an aqueous phase/surfactant ratio at least 2/1. The surfactant system may contain, in addition to the hydrophilic and lipophilic surfactants, cosurfactants and polar organic solvents. The reagent solution comprises aqueous solutions of an additive selected from the group consisting of inorganic oxidizing agents, low molecular weight polar organic oxidizing agents, and nitrogen oxide-containing compounds which act as cetane improvers and/or combustion modifiers. These additives offset the well-known loss in cetane number and/or the ignition delay caused by dispersed or microemulsified water and eliminate the need to change engine operating parameters.

Inventors

  • 👤 Michael David Sexton
  • 👤 Anthony Kitson Smith
  • 👤 Jan Bock
  • 👤 Max Leo Robbins
  • 👤 Salvatore James Pace
  • 👤 Patrick Gerard Grimes

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-23 18:34
CPC Classifications
C; C10; C10L; C10L10/00; C10L10/02; C10L1/00; C10L1/32; C10L1/328; C10L10/12; F; F02; F02B; F02B3/00; F02B3/06

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 156 words
A fuel composition which comprises: (a) a fuel; (b) about 1.0 to about 30.0 weight percent of water based upon said diesel fuel; (c) about 0 to about 30 weight percent of an alkanol based upon said water, said alkanol having about 1 to about 3 carbon atoms; (d) less than about 20.0 weight percent of an additive based upon said water, said additive being selected from the group consisting of an inorganic oxidizer, a polar organic oxidizer and a nitrogen oxide-containing compound; and (e) about 0.5 to about 15.0 weight percent of a surfactant system based on said diesel fuel, said surfactant system comprising a blend of a hydrophilic surfactant and a lipophilic surfactant in a ratio sufficient to form a single phase translucent microemulsion, wherein said diesel fuel exhibits improved cetane and combustion properties, reduced smoke, soot emissions, particulate emissions and NOx emissions in the combustion of said diesel fuel in a diesel engine.
Claim 2
Dependent Claim 19 words
A fuel composition according to claim 1, wherein the fuel is diesel, gasoline or jet fuel, preferably diesel fuel.
Claim 3
Dependent Claim 238 words
A fuel composition according to claim 1 or 2, wherein the hydrophilic and lipophilic blend of surfactants is comprised of two or more surfactants selected from one or more of: (a) an alkali metal, ammonium, alkyl ammonium, alkanol ammonium, or ethoxylated alkyl or alkanol ammonium salt of an alkyl or alkylaryl sulfonic acid of the generic formula: R-SO₃H wherein R is an alkyl or alkyl benzene group containing 8 to 30 carbon atoms in the alkyl chain and the benzene ring may be additionally substituted with one or two alkyl groups containing 1-3 carbon atoms each; (b) an ethoxylated surfactant of the generic formula: R₁x(CH₂CH₂O) n Y wherein R₁ is an alkyl or mono- or di-alkyl aryl group containing 8 to 30 carbon atoms, and Y is -H-,-SO₃-M⁺ or-(PO₃H)-M⁺ wherein M⁺ is an inorganic or ammonium cation including alkyl substituted ammonium cations; R₂ is an alkyl group containing 1 to 20 carbon atoms or a polyethoxy ether group containing from 1 to 30 (CH₂CH₂O) groups; R₃ is H or an alkyl group containing 1 to 3 carbon atoms; R₄ is a polyhydroxy group derived from glycerol, glycols, sorbitol, or various sugars; and n is an integer of from 1 to 30; and (c) an alkali metal, ammonium, alkyl ammonium, alkanol ammonium, or ethoxylated alkyl ammonium salt of an alkyl carboxylic acid of the generic formula R′-COOH wherein R′ is an alkyl group of 8 to 24 carbon atoms.
Claim 4
Dependent Claim 37 words
The composition of claim 3 wherein at least one of the lipophilic surfactants is an ethoxylated C₁₂-C₁₈ alkyl ammonium salt of a C₉ -C₂₄ alkyl carboxylic or alkylaryl sulfonic acid containing less than 6 ethylene oxide groups.
Claim 5
Dependent Claim 38 words
The composition of claim 3 or 4 wherein at least one of the hydrophilic surfactants is an ethoxylated C₁₂-C₁₈ alkyl ammonium salt of a C₉-C₂₄ alkyl carboxylic or alkylaryl sulfonic acid containing 6 or more ethylene oxide groups.
Claim 6
Dependent Claim 93 words
A process for reducing smoke, soot emissions, particulate emissions, and NOx emissions in the combustion of a diesel fuel in a diesel engine which comprises the step of adding to said diesel fuel about 1.0 to about 30.0 weight percent of water and about 0.5 to about 15.0 weight percent of a surfactant system, based on said diesel fuel, said surfactant system comprising a blend of a hydrophilic surfactant and a lipophilic surfactant in a ratio sufficient to form a single phase translucent microemulsion, whereby smoke, soot, particulate and NOx emissions are reduced.
Claim 7
Dependent Claim 63 words
A process according to claim 6, wherein said hydrophilic surfactant is selected from the group consisting of alkali metal, ammonium, 1 to 3 carbon alkyl ammonium, 2 to 6 carbon alkanol ammonium containing 1 to 3 hydroxy groups, and 6 or more ethoxy C₁₂-C₁₈ alkyl ammonium salts of alkyl carboxylic acids and alkyl aryl sulfonic acids and 6 or more ethoxy alkyl phenols.
Claim 8
Dependent Claim 42 words
A process according to claim 6 or 7, wherein said lipophilic surfactant is selected from the group consisting of less than 6 ethoxy alkyl phenols and less than 6 ethoxy C₁₂-C₁₈ alkyl ammonium salts of alkyl carboxylic and alkyl aryl sulfonic acids.

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