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EP0370646A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Apparatus and method for the manufacture of absorbent materials

Assignee: Nippon Shokubai Co Ltd
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Filing: 1989-11-02
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Granted: —
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Expires: 2009-11-02
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Abstract

Abstract It is an object of the invention to present a method of easily and efficiently manufacturing an absorbent material having an absorbent polymer firmly fixed to a substrate, exhibiting an excellent absorption capacity without the polymer dropping off the substrate even after swelling of the polymer, and very low in the residual monomer in the absorbent polymer. This invention relates to a method of preparation of an absorbent material in which an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into an absorbent polymer by polymerization is applied to a substrate, and the monomer is polymerized while the substrate to which the aqueous solution is applied is, on both the sides, held in contact with polymerization-inert surfaces facing each other. The invention also relates to a continuous manufacturing method of an absorbent material characterized by continuously passing in the sequence of 1. the region of applying to a substrate an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into an absorbent polymer by polymerization, and 2. the region of polymerizing the monomer in the state of holding the substrate, on both the sides, in contact with polymerization-inert surfaces facing each other, while moving the substrate. The invention further relates to a manufacturing apparatus of an absorbent material comprising the following means (1) and (2) arranged along the moving route of the substrate for applying to the substrate, while moving the substrate continuously, an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into an absorbent polymer by polymerization, polymerizing the monomer under a condition that the substrate is, on both the sides, held in contact with polymerization-inert surfaces facing each other, and thereby fixing the absorbent polymer to the substrate. (1) Means for applying to a moving substrate an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into an absorbent polymer by polymerization. (2) Polymerization means possessing facing polymerization-inert surfaces and means for setting a gap of a clearance corresponding to the thickness of the substrate between the facing polymerization-inert surfaces, for polymerizing the monomer, while the substrate to which the aqueous solution is applied is passing through the gap to fix the absorbent polymer to the substrate.

Inventors

  • 👤 Koji Miyake
  • 👤 Nobuyuki Harada
  • 👤 Kazumasa Kimura
  • 👤 Tadao Shimomura

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-23 08:45
CPC Classifications
D; D06; D06M; D06M14/00; D06M14/08

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 76 words
A manufacturing method of absorbent composite comprising a step of applying to a substrate an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into absorbent polymer by polymerization, and a step of polymerizing said monomer under a condition that the substrate applied with said aqueous solution is, on both the sides, held in contact with polymerization-inert surfaces facing each other, and thereby manufacturing an absorbent composite.
Claim 2
Dependent Claim 76 words
A manufacturing method of absorbent composite comprising a step of applying to a substrate an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into absorbent polymer by polymerization, and a step of polymerizing said monomer under a condition that the substrate applied with said aqueous solution is, on both the sides, held in contact with polymerization-inert surfaces facing each other, and thereby manufacturing an absorbent composite.
Claim 3
Dependent Claim 31 words
A manufacturing method of absorbent composite according to claim 1, wherein the substrate to which the formed absorbent polymer is fixed after polymerization of said monomer is dried in a gas.
Claim 4
Dependent Claim 81 words
A continuous manufacturing method of absorbent composite for continuously passing a substrate, while moving, in the sequence of; (1) an application region for applying to the substrate an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into an absorbent polymer by polymerization, and (2) a polymerization region for polymerizing the monomer under a condition that the substrate is, on both the sides, held in contact with polymerization-inert surfaces facing each other.
Claim 5
Dependent Claim 81 words
A continuous manufacturing method of absorbent composite for continuously passing a substrate, while moving, in the sequence of; (1) an application region for applying to the substrate an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into an absorbent polymer by polymerization, and (2) a polymerization region for polymerizing the monomer under a condition that the substrate is, on both the sides, held in contact with polymerization-inert surfaces facing each other.
Claim 6
Dependent Claim 35 words
A continuous manufacturing method of absorbent composite according to claim 3, wherein the substrate is passed through a drying region for heating the substrate, after said polymerization region, while keeping the substrate in a gas.
Claim 7
Dependent Claim 90 words
A continuous manufacturing method of absorbent composite for passing a substrate applied with an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into absorbent polymer by polymerization, continuously in the sequence of: (1) a polymerization region for polymerizing the monomer in a state that the substrate is, on both the sides, held in contact with polymerization-inert surfaces facing each other, and (2) a drying region for heating the substrate while keeping in a gas, thereby continuously manufacturing an absorbent composite.
Claim 8
Dependent Claim 90 words
A continuous manufacturing method of absorbent composite for passing a substrate applied with an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into absorbent polymer by polymerization, continuously in the sequence of: (1) a polymerization region for polymerizing the monomer in a state that the substrate is, on both the sides, held in contact with polymerization-inert surfaces facing each other, and (2) a drying region for heating the substrate while keeping in a gas, thereby continuously manufacturing an absorbent composite.
Claim 9
Dependent Claim 42 words
A continuous manufacturing method according to claim 4 or 5, wherein the drying region is for heating by hot gas, microwaves, infrared rays or ultraviolet rays, while holding the substrate in a gas by means of rotatable support roll and/or support belt.
Claim 10
Dependent Claim 27 words
A manufacturing method according to any one of claims 1 to 6, wherein said water-soluble ethylenically unsaturated monomer is mainly composed of (meth)acrylic acid or its salt.
Claim 11
Dependent Claim 21 words
A manufacturing method according to any one of claims 1 to 7, wherein said polymerization is effected by heating said substrate.
Claim 12
Dependent Claim 20 words
A manufacturing method according to claim 8, wherein said heating is conducted in a temperature range of 50 to 150°C.
Claim 13
Dependent Claim 14 words
A manufacturing method according to claim 8, wherein said heating is effected by microwaves.
Claim 14
Dependent Claim 19 words
A manufacturing method according to any one of claims 1 to 10, wherein said substrate is a fibrous substrate.
Claim 15
Dependent Claim 22 words
A manufacturing method according to any one of claims 1 to 11, wherein said aqueous solution contains a water-soluble cross linking agent.
Claim 16
Dependent Claim 21 words
A manufacturing method according to any one of claims 1 to 12, wherein said polymerization-inert surfaces are fluorocarbonresin-treated or mirror-finished surfaces.
Claim 17
Dependent Claim 16 words
An absorbent composite obtained by any one of the manufacturing methods of claims 1 to 13.
Claim 18
Dependent Claim 156 words
A manufacturing apparatus for absorbent composite comprising the following means (1) and (2) arranged along the moving route of a substrate in which while continuously moving the substrate, an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into absorbent polymer by polymerization is applied to the substrate, and the monomer is polymerized under a condition that the substrate is, on both the sides, held in contact with polymerization-inert surfaces facing each other, thereby fixing an absorbent polymer to the substrate. (1) Means for applying said aqueous solution to the moving substrate. (2) Means for polymerization comprising facing polymerization-inert surfaces and means for setting a clearance between the polymerization-inert surfaces to a space corresponding to the thickness of the substrate, being designed to polymerize the monomer while the substrate applied with said aqueous solution is passing through said clearance, thereby fixing an absorbent polymer to the substrate.
Claim 19
Dependent Claim 156 words
A manufacturing apparatus for absorbent composite comprising the following means (1) and (2) arranged along the moving route of a substrate in which while continuously moving the substrate, an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into absorbent polymer by polymerization is applied to the substrate, and the monomer is polymerized under a condition that the substrate is, on both the sides, held in contact with polymerization-inert surfaces facing each other, thereby fixing an absorbent polymer to the substrate. (1) Means for applying said aqueous solution to the moving substrate. (2) Means for polymerization comprising facing polymerization-inert surfaces and means for setting a clearance between the polymerization-inert surfaces to a space corresponding to the thickness of the substrate, being designed to polymerize the monomer while the substrate applied with said aqueous solution is passing through said clearance, thereby fixing an absorbent polymer to the substrate.
Claim 20
Dependent Claim 18 words
A manufacturing apparatus according to claim 15, wherein said polymerization means comprises also means for heating the substrate.
Claim 21
Dependent Claim 24 words
A manufacturing apparatus according to claim 15 or 16, wherein said polymerization means is followed by means for taking up the obtained absorbent composite.
Claim 22
Dependent Claim 34 words
A manufacturing apparatus according to claim 15 or 16, wherein said polymerization means is followed by drying means by heating in a gas while moving the substrate to which the absorbent polymer is fixed.
Claim 23
Dependent Claim 32 words
A manufacturing apparatus according to claim 18, wherein the drying means comprises at least one of hot gas blowing source, microwave applying means, infrared ray irradiating means and ultraviolet ray irradiating means.
Claim 24
Dependent Claim 27 words
A manufacturing apparatus according to claim 19, wherein the drying means further comprises rotatable support roll and/or support belt for holding the moving substrate in a gas.
Claim 25
Dependent Claim 27 words
A manufacturing apparatus according to any one of claims 18 to 20, wherein the drying means is followed by means for taking up the dried absorbent composite.
Claim 26
Dependent Claim 16 words
An absorbent composite manufactured in any one of the manufacturing apparatuses of claims 15 to 21.

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